The new homoleptic rare earth compound [Y(C(SiHMe(2))(3))(3)] () is prepared in 82% yield by salt metathesis of YCl(3) and 3 equivalents of [KC(SiHMe(2))(3)] (); two beta-agostic Y(H-Si) interactions are observed for each C(SiHMe(2))(3) ligand in , giving six agostic interactions per yttrium(iii) center.
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A tris(alkyl)yttrium compound containing six beta-agostic Si-H interactions.
Chem Commun (Camb)
February 2009
Iowa State University and Ames Laboratory, Ames, IA, USA.
The new homoleptic rare earth compound [Y(C(SiHMe(2))(3))(3)] () is prepared in 82% yield by salt metathesis of YCl(3) and 3 equivalents of [KC(SiHMe(2))(3)] (); two beta-agostic Y(H-Si) interactions are observed for each C(SiHMe(2))(3) ligand in , giving six agostic interactions per yttrium(iii) center.
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