Iron-catalyzed carbolithiation of alkynes having no heteroatoms.

Chem Commun (Camb)

Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan.

Published: April 2009

Alkyl- and aryllithium compounds were found to add to alkynes having no heteroatoms in the presence of an iron or iron-copper catalyst to give various trisubstituted vinyllithium compounds.

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Source
http://dx.doi.org/10.1039/b900345bDOI Listing

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