In this Letter, we present a novel strategy to control the thermoelectric properties of individual PbSe nanowires. Using a field-effect gated device, we were able to tune the Seebeck coefficient of single PbSe nanowires from 64 to 193 microV x K(-1). This direct electrical field control of sigma and S suggests a powerful strategy for optimizing ZT in thermoelectric devices. These results represent the first demonstration of field-effect modulation of the thermoelectric figure of merit in a single semiconductor nanowire. This novel strategy for thermoelectric property modulation could prove especially important in optimizing the thermoelectric properties of semiconductors where reproducible doping is difficult to achieve.
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http://dx.doi.org/10.1021/nl900377e | DOI Listing |
Nanoscale
November 2024
State Key Laboratory of Radio Frequency Heterogeneous Integration (Shenzhen University); College of Physics and Optoelectronic Engineering, Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, Shenzhen University, Shenzhen 518060, P. R. China.
ACS Omega
July 2022
Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695-7907, United States.
Screw dislocations play a significant role in the growth of crystalline structures by providing a continuous source of surface steps which represent available sites for crystal growth. Here, we show that pure screw dislocations can become helical from the absorption of defects (e.g.
View Article and Find Full Text PDFNanoscale
March 2019
Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, WA 99352, USA.
We grew binary PbSe nanowires in an in situ gas-heating cell in a transmission electron microscope and elucidated species dependent mass transport pathways and key correlations among supersaturation, nucleation, and growth kinetics, thereby enabling morphological and compositional control of nanowires with tailored properties.
View Article and Find Full Text PDFACS Nano
February 2018
Department of Chemistry, ‡Department of Materials Science and Engineering, and §Department of Electrical and Systems Engineering, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States.
Doping, as a central strategy to control free carrier type and concentration in semiconductor materials, suffers from low efficiency at the nanoscale, especially in systems having high permittivity (ϵ) and large Bohr radii, such as lead chalcogenide nanocrystals (NCs) and nanowires (NWs). Here, we study dielectric confinement effects on the doping efficiency of lead chalcogenides nanostructures by integrating PbSe NWs in the platform of field effect transistors (FETs). Elemental Pb or In or elemental Se is deposited by thermal evaporation to remotely n- or p-dope the NWs.
View Article and Find Full Text PDFNanotechnology
October 2016
Institute of Laser & Opto-Electronics, College of Precision Instruments and Opto-electronics Engineering, Tianjin University, Tianjin 300072, People's Republic of China. Key Laboratory of Opto-electronics Information Technology (Tianjin University), Ministry of Education, Tianjin 300072, People's Republic of China.
Here, vertical field effect phototransistors (VFEPTs) based on lead selenide colloidal quantum dots (PbSe CQDs) for infrared photo detection were investigated, using Au/Ag nanowires as the source transparent electrode. VFEPTs have the advantage of easy fabrication of ultrashort channel length devices, as the channel length is simply determined here by the PbSe CQDs active layer's thickness (260 nm). In ultrashort channels, photo-excited carriers quickly (in nanoseconds) transfer to the drain.
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