AI Article Synopsis

  • The researchers developed a new method to control the thermoelectric properties of PbSe nanowires using a field-effect gated device.
  • They successfully modified the Seebeck coefficient of individual nanowires, enhancing it from 64 to 193 microV x K(-1).
  • This technique marks the first instance of adjusting the thermoelectric figure of merit in a single nanowire, potentially benefiting semiconductors that are hard to dope consistently.

Article Abstract

In this Letter, we present a novel strategy to control the thermoelectric properties of individual PbSe nanowires. Using a field-effect gated device, we were able to tune the Seebeck coefficient of single PbSe nanowires from 64 to 193 microV x K(-1). This direct electrical field control of sigma and S suggests a powerful strategy for optimizing ZT in thermoelectric devices. These results represent the first demonstration of field-effect modulation of the thermoelectric figure of merit in a single semiconductor nanowire. This novel strategy for thermoelectric property modulation could prove especially important in optimizing the thermoelectric properties of semiconductors where reproducible doping is difficult to achieve.

Download full-text PDF

Source
http://dx.doi.org/10.1021/nl900377eDOI Listing

Publication Analysis

Top Keywords

pbse nanowires
12
field-effect modulation
8
seebeck coefficient
8
coefficient single
8
single pbse
8
novel strategy
8
thermoelectric properties
8
optimizing thermoelectric
8
thermoelectric
5
modulation seebeck
4

Similar Publications

One-pot synthesis of heterostructured CsPbBr/PdSe nanowires with excellent humidity stability.

Nanoscale

November 2024

State Key Laboratory of Radio Frequency Heterogeneous Integration (Shenzhen University); College of Physics and Optoelectronic Engineering, Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, Shenzhen University, Shenzhen 518060, P. R. China.

Article Synopsis
  • Lead halide perovskite nanowires (NWs) are promising due to their unique features like efficient carrier transport and polarized light emission, but their instability poses challenges for practical use.
  • Researchers successfully synthesized heterostructured CsPbBr/PbSe NWs, measuring 10 nm in diameter, which emitted green fluorescence with a strong quantum yield of 37.6%.
  • These NWs showed impressive stability in water and air over several months, paving the way for their potential use in optoelectronic devices.
View Article and Find Full Text PDF

Discovery of Double Helix and Impact on Nanoscale to Mesoscale Crystalline Structures.

ACS Omega

July 2022

Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695-7907, United States.

Screw dislocations play a significant role in the growth of crystalline structures by providing a continuous source of surface steps which represent available sites for crystal growth. Here, we show that pure screw dislocations can become helical from the absorption of defects (e.g.

View Article and Find Full Text PDF

In situ characterization of kinetics and mass transport of PbSe nanowire growth via LS and VLS mechanisms.

Nanoscale

March 2019

Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, WA 99352, USA.

We grew binary PbSe nanowires in an in situ gas-heating cell in a transmission electron microscope and elucidated species dependent mass transport pathways and key correlations among supersaturation, nucleation, and growth kinetics, thereby enabling morphological and compositional control of nanowires with tailored properties.

View Article and Find Full Text PDF

The Effect of Dielectric Environment on Doping Efficiency in Colloidal PbSe Nanostructures.

ACS Nano

February 2018

Department of Chemistry, ‡Department of Materials Science and Engineering, and §Department of Electrical and Systems Engineering, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States.

Doping, as a central strategy to control free carrier type and concentration in semiconductor materials, suffers from low efficiency at the nanoscale, especially in systems having high permittivity (ϵ) and large Bohr radii, such as lead chalcogenide nanocrystals (NCs) and nanowires (NWs). Here, we study dielectric confinement effects on the doping efficiency of lead chalcogenides nanostructures by integrating PbSe NWs in the platform of field effect transistors (FETs). Elemental Pb or In or elemental Se is deposited by thermal evaporation to remotely n- or p-dope the NWs.

View Article and Find Full Text PDF

High performance PbSe colloidal quantum dot vertical field effect phototransistors.

Nanotechnology

October 2016

Institute of Laser & Opto-Electronics, College of Precision Instruments and Opto-electronics Engineering, Tianjin University, Tianjin 300072, People's Republic of China. Key Laboratory of Opto-electronics Information Technology (Tianjin University), Ministry of Education, Tianjin 300072, People's Republic of China.

Here, vertical field effect phototransistors (VFEPTs) based on lead selenide colloidal quantum dots (PbSe CQDs) for infrared photo detection were investigated, using Au/Ag nanowires as the source transparent electrode. VFEPTs have the advantage of easy fabrication of ultrashort channel length devices, as the channel length is simply determined here by the PbSe CQDs active layer's thickness (260 nm). In ultrashort channels, photo-excited carriers quickly (in nanoseconds) transfer to the drain.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!