The complexes [Cp*E{W(CO)5}2] (E=P, As; Cp*=C5Me5) react with 1,2-diphosphinobenzene to give 1,2,3-triphosphole and 2-arsa-1,3-diphosphole derivatives as reactive intermediates that dimerise to polycyclic phosphorous and arsenic containing cage compounds.
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