Long live lubricants: The selective capture of water from lubricants using nanosized microporous aluminophosphate (AEI) and aluminosilicate materials was studied. Nearly 98 % of the moisture was removed from the lubricating oil under ambient conditions, resulting in a significant improvement in the lubricating service lifetime. Moreover, both the lubricant and the microporous sorbents can be recovered and reused.The selective capture of water from lubricants using nanosized microporous aluminophosphate and aluminosilicate materials was studied with an aim to increase the lifetime of the lubricating mineral oil. The amount of water present in oxidized lubricating oil before and after treatment with microporous materials was studied by FTIR spectroscopy and determined quantitatively using the Karl Fischer titration method. Nanosized aluminophosphate revealed a high selectivity for water without adsorbing other additives, in contrast to nanosized aluminosilicates which also adsorb polar oxidation products and ionic additives. About 98 % of the initial moisture could be removed from the lubricating oil under ambient conditions, resulting in a significant improvement in the lubricating service lifetime. Moreover, no by-products are formed during the process and both the lubricant and the sorbents can be recovered and reused, thus the method is environmentally friendly.
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http://dx.doi.org/10.1002/cssc.200800234 | DOI Listing |
ChemSusChem
January 2025
Forestry and Forest Products Research Institute: Shinrin Sogo Kenkyujo, Center for Advanced Materials, 1 Matsunosato, 305-8687, JAPAN.
Although microporous carbons can perform well for CO2 separations under high pressure conditions, their energy-demanding regeneration may render them a less attractive material option. Here, we developed a large-pore mesoporous carbon with pore sizes centered around 20-30 nm using a templated technical lignin. During the soft-templating process, unique cylindrical supramolecular assemblies form from the copolymer template.
View Article and Find Full Text PDFChemosphere
January 2025
US Army Corps of Engineers, Engineer Research and Development Center, Environmental Laboratory, Vicksburg, MS, 39180, United States. Electronic address:
Per- and polyfluoroalkyl substances (PFAS) are environmentally persistent contaminants that are often referred to as "Forever Chemicals". They are used in industrial and household products; however, they are resistant to degradation. Thus, PFAS contamination has become a wide-spread issue.
View Article and Find Full Text PDFPublic Health
January 2025
Department of Surgery, Brody School of Medicine at East Carolina University, Greenville, NC, USA.
Objective: To develop and validate a county deprivation index (CDI) that assesses socio-economic disparities and their impact on health outcomes at the county level.
Study Design: A retrospective, cross-sectional study using publicly available county-level data.
Methods: Hierarchical cluster analysis was used to group 18 county-level socio-economic indicators into three clusters: economic well-being and technical connectivity, socio-economic disadvantage and vulnerability, and housing affordability and quality of life.
Waste Manag
January 2025
School of Transportation Science and Engineering, Harbin Institute of Technology, Harbin 150090, China. Electronic address:
The accumulation of construction solid waste (CSW) leads to the waste of land resources and environmental pollution, becoming a significant social problem. Identifying the amount of high-value CSW is essential for assessing the value of accumulated CSW and formulating appropriate recycling strategies. With the development of machine learning technology, CSW recognition techniques combining image acquisition devices and convolutional neural networks have been widely applied.
View Article and Find Full Text PDFTalanta
January 2025
School of Pharmaceutical Sciences, Wenzhou Medical University, Wenzhou, 325035, China. Electronic address:
Hepatocellular carcinoma (HCC) stands as a grave illness characterized by elevated death rates. Early identification plays a vital role in improving patient survival. Herein, a novel split-type dual-mode biosensor featuring with near-infrared photoelectronchemical (PEC) and colorimetric sensing characteristics was developed for the high-performance detection of HepG2 cells.
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