A chiral calix[4]arene bearing l-2,3-dibenzoyltartaric acid groups at the lower rim was synthesized and could enantioselectively self-assemble to result in a gel or suspension only with one enantiomer of chiral amines; as revealed by electron microscopy, the resultant gel was of nanofibers with a high aspect ratio but the suspension was composed of nanospheres.
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| http://dx.doi.org/10.1039/b817974c | DOI Listing |
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