A closer look: Investigation of the reduction properties of a single Fischer-Tropsch catalyst particle, using in situ scanning transmission X-ray microscopy with spatial resolution of 35 nm, reveals a heterogeneous distribution of Fe(0), Fe(2+), and Fe(3+) species. Regions of different reduction properties are defined and explained on the basis of local chemical interactions and catalyst morphology.
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http://dx.doi.org/10.1002/anie.200806003 | DOI Listing |
Materials (Basel)
December 2024
School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an 710129, China.
Developing highly efficient and cost-competitive electrocatalysts for the hydrogen evolution reaction (HER), which can be applied to hydrogen production by water splitting, is of great significance in the future of the zero-carbon economy. Here, by means of first-principles calculations, we have scrutinized the HER catalytic capacity of single-atom catalysts (SACs) by embedding transition-metal atoms in the C and Mo vacancies of a tetragonal MoC slab, where the transition-metal atoms refer to Ti, V, Cr, Mn, Fe, Co, Ni and Cu. All the MoC-based SACs exhibit excellent electrical conductivity, which is favorable to charge transfer during HER.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Institute of Natural Sciences and Mathematics, Ural Federal University, 620002 Yekaterinburg, Russia.
The development and characterization of synthesis techniques for oxide materials based on ceria is a subject of extensive study with the objective of their wide-ranging applications in pursuit of sustainable development. The present study demonstrates the feasibility of controlled synthesis of CeMO (M = Fe, Ni, Co, Mn, Cu, Ag, Sm, Cs, x = 0.0-0.
View Article and Find Full Text PDFInt J Mol Sci
December 2024
School of Agricultural Engineering and Food Science, Shandong University of Technology, Zibo 255000, China.
In the electrocatalytic (EC) degradation process, challenges such as inefficient mass transfer, suboptimal mineralization rates, and limited current efficiency have restricted its broader application. To overcome these obstacles, this study synthesized spherical particle electrodes (FeNi@BC) with superior electrocatalytic performance using a bio-inspired preparation method. A three-dimensional electrocatalytic oxidation system based on FeNi@BC electrode, EC/FeNi@BC, showed excellent degradation efficiency of sulfamethoxazole (SMX), reaching 0.
View Article and Find Full Text PDFJ Environ Manage
January 2025
Universidad Autónoma de Nuevo León, Facultad de Agronomía, Laboratorio de Ciencias Naturales, General Escobedo, 66050, Nuevo Leon, Mexico. Electronic address:
The chemical co-precipitation method was used to synthesize a variety of pure BiO and substituted BiCoCdO NPs (x = 0.0-0.8) and doping influences were evaluated based on the optical, photocatalytic, morphological, and structural characteristics.
View Article and Find Full Text PDFSmall
January 2025
Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education of the People's Republic of China, Heilongjiang University, Xuefu Road, Harbin, 150080, P. R. China.
The bi-transition-metal interstitial compounds (BTMICs) are promising for water electrolysis. The previous BTMICs are usually composed of irregular particles. Here, this work shows the synthesis of novel 1D CoMoC-based heterojunction nanowires (1D Co/CoMoC) with diameters about 50 nm and a length-to-diameter ratio about 20 for efficient water electrolysis.
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