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Switching the chirality of single adsorbate complexes. | LitMetric

Switching the chirality of single adsorbate complexes.

Angew Chem Int Ed Engl

Nanoscale Materials Science, Empa, Swiss Federal Laboratories for Materials Testing and Research, Ueberlandstrasse 129, 8600 Dübendorf, Switzerland.

Published: June 2009

Pumped up: Propene molecules form chiral complexes when adsorbed on a copper surface. Inelastically scattered tunneling electrons from the tip of a scanning tunneling microscope induce rotation or diffusion of the adsorbate on the surface. Higher tunneling currents can lead to conversion of the adsorbate into the opposite enantiomer.

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Source
http://dx.doi.org/10.1002/anie.200805740DOI Listing

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