The contact electrodes of printed organic thin-film transistors (OTFTs) were fabricated by direct printing using patterned hard poly(dimethylsiloxane) (h-PDMS) stamp with injection channel onto flexible poly(ethylenenaphthalate) (PEN) plastic substrates, wherein low-viscosity and low-resistance conductive nanoparticle silver (Ag) ink was injected. The source and drain electrodes (W/L = 500 microm/5 microm, 500 microm/10 microm, and 500 microm/20 microm) of printed OTFT were fabricated by direct printing. The printed OTFT with polyvinylphenol (PVP) as polymer dielectric layer was formed by spin coating and poly(3-hexylthiopene-2,5-dily) (P3HT) as organic semiconductor layer was ink-jet printing. The printed OTFT was characterized in air and the following parameters were obtained: a mobility of 0.06 (+/- 0.02) cm2/Vs, an on/off current ratio of 10(4) and a subthreshold slope of 2.53 V/decade. The direct printing using patterned h-PDMS stamp for ink injection patterning made it be possible to fabricate printed OTFT with a channel length as below as to 5 microm. The number of steps in the fabrication process was reduced by 20 steps compared with photolithography.
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http://dx.doi.org/10.1166/jnn.2008.1122 | DOI Listing |
Micromachines (Basel)
March 2024
Department of Electronic Engineering, Universitat Autònoma de Barcelona, 08193 Bellaterra, Spain.
Given the current maturity of printed technologies, Organic Thin-Film Transistors (OTFT) still show high initial variability, which can be beneficial for its exploitation in security applications. In this work, the process-related variability and aging of commercial OTFTs have been characterized to evaluate the feasibility of OTFTs-based Physical Unclonable Functions (PUFs) implementation. For our devices, -based PUFs show good uniformity and uniqueness.
View Article and Find Full Text PDFSci Rep
October 2022
Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba, 277-8561, Japan.
Organic thin-film transistors (OTFTs) are promising building blocks of flexible printable electronic devices. Similar to inorganic FETs, OTFTs are heterostructures consisting of metals, insulators, and semiconductors, in which nanoscale interfaces between different components should be precisely engineered. However, OTFTs use noble metals, such as gold, as electrodes, which has been a bottleneck in terms of cost reduction and low environmental loading.
View Article and Find Full Text PDFAcc Chem Res
March 2022
Material Innovation Research Center (MIRC) and Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan.
ACS Appl Mater Interfaces
October 2021
School of Chemical Engineering, Yeungnam University, Gyeongsan 38541, Republic of Korea.
Herein, printable polymer series containing different portions of cinnamate and perfluorinated phenyl functionalities, namely, polyperfluorostyrene--poly(vinylbenzyl cinnamates) (PFS--PVBCi (:)) copolymers, were synthesized and applied as gate dielectrics for organic thin-film transistors (OTFTs). The polymeric dielectrics were successfully printed via electrostatic force-assisted dispensing mode of electrohydrodynamic jet printing. The dielectric characteristics of the printed polymers, such as surface energy, dielectric constant, leakage current, atomic depth profiles, and deposited semiconducting layer characteristics, were clearly identified.
View Article and Find Full Text PDFACS Appl Mater Interfaces
March 2021
School of Materials Engineering, Neil Armstrong Hall of Engineering, Purdue University, 701 West Stadium Avenue, West Lafayette, Indiana 47907-2050, United States.
The inkjet printing of metal electrodes on polymer films is a desirable manufacturing process due to its simplicity but is limited by the lack of thermal stability and serious delaminating flaws in various aqueous and organic solutions. Kapton, adopted worldwide due to its superior thermal durability, allows the high-temperature sintering of nanoparticle-based metal inks. By carefully selecting inks (Ag and Au) and Kapton substrates (Kapton HN films with a thickness of 135 μm and a thermal resistance of up to 400 °C) with optimal printing parameters and simplified post-treatments (sintering), outstanding film integrity, thermal stability, and antidelaminating features were obtained in both aqueous and organic solutions without any pretreatment strategy (surface modification).
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