The Sc(OTf)(3)-catalyzed C-C bond formation by direct alkylation of quinolines and pyridines using simple alkanes was developed. Various alkanes reacted with quinolines and pyridines to give the corresponding alkylation products in 50-91% yields in the presence of tert-butyl peroxide.
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| http://dx.doi.org/10.1021/ol900070x | DOI Listing |
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