Highly ordered TiO(2) nanotubes were successfully fabricated using a nanoporous alumina templating method. A modified sol-gel route was used to infiltrate the alumina pores with Ti(OC(3)H(7))(4) which was subsequently converted into TiO(2) nanotubes. The average external diameter, tube lengths, and wall thickness achieved were 295 nm, 6-15 microm, and 21-42 nm, respectively. Diffraction data reveals that the nanotubes consist solely of the anatase phase. Dye-sensitized solar cells using TiO(2) nanotube arrays as the working electrode yielded power conversion efficiencies as high as 3.5% with a maximum incident photon-to-current conversion efficiency of 20% at 520 nm.
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http://dx.doi.org/10.1021/nl802818d | DOI Listing |
Biotechnol Bioeng
January 2025
National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou, PR China.
Based on the innate sensitivity of cell to substrate topographical cues, modulating cell-directed growth behavior is crucial for promoting tissue repair and reconstruction. Although photolithography technology has been extensively employed to fabricate a variety of anisotropic patterned structures to guide cell growth, it remains a great challenge to design high-resolution micro/nano hierarchical structures directly onto medical titanium (Ti)-based implants. Herein, we present a rapid, reliable and reproducible approach combining photolithography and hydrothermal technology to construct a micro/nano hierarchical structure including anisotropic micro-strips and a porous structure composed of TiO nanotubes features.
View Article and Find Full Text PDFPolymers (Basel)
January 2025
Department of Chemical Engineering, Dr B R Ambedkar National Institute of Technology, Jalandhar 144011, Punjab, India.
Antimicrobial polymeric coatings rely not only on their surface functionalities but also on nanoparticles (NPs). Antimicrobial coatings gain their properties from the addition of NPs into a polymeric matrix. NPs that have been used include metal-based NPs, metal oxide NPs, carbon-based nanomaterials, and organic NPs.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
Departamento de Química Orgánica, Universidad de Zaragoza, 50009 Zaragoza, Spain.
Dye-sensitization is a promising strategy to improve the light absorption and photoactivity abilities of wide-bandgap semiconductors, like TiO. For effective water-splitting photoanodes with no sacrificial agents, the electrochemical potential of the dye must exceed the thermodynamic threshold needed for the oxygen evolution reaction. This study investigates two promising organic cyanoacrylic dyes, designed to meet that criterion by means of theoretical calculations.
View Article and Find Full Text PDFDalton Trans
January 2025
The Department of Chemistry, Karadeniz Technical University, 61080, Trabzon, Turkey.
The utilisation of implantable medical devices has become safer and more prevalent since the establishment of sterilisation methods and techniques a century ago. Nevertheless, device-associated infections remain a significant and growing concern, particularly in light of the continued rise in the number of medical device implantations. This underscores the imperative for the development of efficacious prevention and treatment strategies for device-associated infections, as well as further investigation into the design of innovative antibacterial surfaces for medical device applications.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Centre for Plasma and Laser Engineering, Institute of Fluid-Flow Machinery, Polish Academy of Sciences, 14 Fiszera Street, 80-231 Gdańsk, Poland.
Research on titanium nanotubes modified with metal sulfides, particularly bismuth sulfide (BiS), aims to create heterostructures that efficiently absorb sunlight and then separate photogenerated charge carriers, thereby enhancing the energy conversion efficiency. This study shows a key role of solvent used for sulfide and bismuth salt solutions used during successive ionic layer adsorption and reaction (SILAR) onto the morphology, structure, and photoresponse of the heterojunction where one element is represented by semitransparent titania nanotubes (gTiNT) and the second is BiS. Using 2-methoxyethanol and methanol during SILAR, results in remarkably photoactive 3D heterostructure and recorded photocurrents were 44 times higher compared to bare titania nanotubes.
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