Redox-responsive recombination of carbon-carbon bonds on flexible tetrairon cores.

J Am Chem Soc

International Research Center for Elements Science (IRCELS), Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.

Published: February 2009

When a brown powder of 2a was dissolved in acetonitrile, 2a was converted to 2b. Equilibrium was reached at a 74:26 molar ratio within 1 week at 303 K. The isomerization proceeds through a cubane-like transition state, in which recombination of a carbon-carbon bond occurs.

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http://dx.doi.org/10.1021/ja809540wDOI Listing

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