Surfactant foam was used to remove absorbed hydrocarbons from soils. The nature and extent of the foam pathway decide the efficiency of this technology. The characteristics and behavior of foam flow are difficult to visually observe. In this study, laboratory sandbox experiments were performed to estimate the flow behavior of surfactant foam and thus elucidate the properties and flow behavior of surfactant foam. To quantitatively determine the distribution of foam and evaluate accurately the flow field of foam in the soil, this study designed a special technique, applying micro-scale iron powder as a tracer. The foam generated with 4% (w/v) mixed solution of Span 60 and sodium dodecyl sulfate (SDS) showed an excellent stability and quality, which made it particularly apt for this study. The results indicated that the foam flows through the zone above the clay planes and also flows through the zone between the clay planes. The heterogeneous sand does not inhibit the invasion of foam flow. Moreover, the results of tracer tests and photographs of the foam distributions in sandbox were identical in the behavior of foam flow. This knowledge is valuable for providing insight into the foam remediation of contaminated soil.
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http://dx.doi.org/10.1016/j.jhazmat.2008.12.038 | DOI Listing |
Heliyon
January 2025
Department of Chemical Engineering, Quchan Branch, Islamic Azad University, Quchan, Iran.
An interface can be delicately designed using interactions between nanoparticles and surfactants by controlling surface properties such as activity and charge equilibrium. This study seeks to provide insights into how surfactant concentration impacts the stability and dynamics of nanoparticle-surfactant interfaces, with potential applications in material science and interface engineering. This study investigates the interactions between Graphene Function (Gr, Graphene function in this text refers to functionalizing the graphene sheets with -COOH groups via acidic reactions.
View Article and Find Full Text PDFLangmuir
January 2025
School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, PR China.
Aqueous film-forming foam (AFFF) is a targeted product for liquid fuel fires and has the benefits of a long storage period and high fire extinguishing efficiency. However, because of the toxicity and bioaccumulation of the core raw material's long-chain fluorocarbon surfactant, traditional AFFF is being phased out. For this reason, three efficient AFFFs (F-1, F-2, and F-3; more details in Table 2) were designed using anionic surfactants (PBAF) with branched C perfluorinated chains, hexadecyltrimethylammonium bromide (CTAB), and dodecyl dimethyl betaine (BS-12) as core materials.
View Article and Find Full Text PDFSci Rep
January 2025
School of Chemical, Petroleum and Gas Engineering, Iran University of Science and Technology (IUST), P.O. Box 16844-13114, Tehran, Iran.
Surfactant chemistry can affect the phenolic foam (PF) properties by controlling the collision and combination of the created bubbles during foam production. The study was accomplished using two surfactant families, nonionic: polysorbate (Tween80) and anionic: sodium and ammonium lauryl sulfates (SLS30 and ALS70) and sodium laureth sulfate (SLES270) to manufacture PF foams. Tween80 and SLS30 resulted in foams with the lowest and highest densities, 20.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
Department of Aquatic Sciences and Assessment, Swedish University of Agricultural Sciences, Uppsala 75651, Sweden.
Per- and polyfluoroalkyl substances (PFAS)-containing firefighting foam have been used in stationary fire suppression systems for several decades. However, there is a lack of research on how to decontaminate PFAS-contaminated infrastructure and evaluate treatment efficiency. This study assessed the removal of PFAS from stainless steel pipe surfaces using different cleaning agents (tap water, methanol, and aqueous solutions containing 10 and 20 wt % of butyl carbitol (BC)) at different temperatures (20 °C, 40 °C, and 70 °C).
View Article and Find Full Text PDFACS Omega
January 2025
Cracow University of Technology, Faculty of Chemical Engineering and Technology, Warszawska 24, Cracow 31-155, Poland.
Surface-active agents are widely used in industrial processes and products for daily use. Surfactants are essential in consumer products, although they are environmentally harmful. Consequently, new technologies are being sought to address the surfactant waste problem effectively.
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