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Synthesis of diazacalix[8]arene and triazacalix[12]arene methyl ethers via intramolecular aryl amination. | LitMetric

Synthesis of diazacalix[8]arene and triazacalix[12]arene methyl ethers via intramolecular aryl amination.

Org Lett

Department of Chemistry, California State University, Sacramento, 6000 J Street, Sacramento, California 95819, USA.

Published: February 2009

Azacalixarenes derived from p-tert-butylphenol are generated by an intramolecular aryl amination strategy as the ring-closing step. The reaction produces the first examples of larger p-tert-butylcalixarenes with regioselective substitution of bridging methylenes with nitrogen atoms.

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Source
http://dx.doi.org/10.1021/ol8028912DOI Listing

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