The use of the liquid-crystalline phase of fragmented DNA solution for enantiomeric differentiation by NMR is reported. The lyotropic cholesteric liquid crystal system formed, orients in a magnetic field and is able to discriminate water soluble enantiomeric mixtures in a simple 2D J-resolved NMR experiment.

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http://dx.doi.org/10.1021/jp806534vDOI Listing

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