The condition under which the Wenzel or Cassie equation correctly estimates the most stable contact angle is reiterated and demonstrated: these equations do hold when the drop size is sufficiently large compared with the wavelength of roughness or chemical heterogeneity. The numerical demonstrations somewhat mimic recent experiments that seemingly refuted the Wenzel and Cassie equations and show that these experiments were performed only for drops of sizes similar in order of magnitude to the wavelength of roughness or chemical heterogeneity. Under such conditions, the Wenzel and Cassie equations are a priori not expected to be valid. It is also explained that both the local equilibrium condition at the contact line and the global equilibrium condition involving the wetted area within the contact line are necessary and complementary.
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http://dx.doi.org/10.1021/la802667b | DOI Listing |
Sci Rep
January 2025
Department of Mechanics, School of Civil Engineering, Architecture and Environment, Hubei University of Technology, Wuhan, 430068, People's Republic of China.
Droplets impinging on sparse microgrooved polydimethylsiloxane (PDMS) surfaces with different solid fractions was experimentally investigated. First, wettability and stability of droplets on these surfaces was analyzed. The advancing and receding contact angles were found to have a large difference between in the longitudinal direction and in the transverse one, which could be attributed to the anisotropy of the micropatterned surfaces.
View Article and Find Full Text PDFLangmuir
January 2025
School of Chemical Engineering, Department of Chemistry and Materials Science, Aalto University, Tietotie 3 Espoo 02150, Finland.
Superhydrophobic surfaces find applications in numerous biomedical scenarios, requiring the repellence of biofluids and biomolecules. Plastron, the trapped air between a superhydrophobic surface and a wetting liquid, plays a pivotal role in biofluid repellency. A key challenge, however, is the often short-lived plastron stability in biofluids and the lack of knowledge surrounding it.
View Article and Find Full Text PDFSmall
December 2024
Department of Fiber Convergence Material Engineering, Dankook University, Gyeonggi-Do, 16890, Republic of Korea.
Approximately 2 billion people still lack access to clean drinking water. Extensive efforts are underway to develop semiconductor photocatalysts for water disinfection and environmental remediation, but conventional liquid-solid diphase interfacial photocatalysts face challenges like low diffusion coefficients and limited solubility of dissolved oxygen. This study introduces freestanding copper oxide fluffy pine needle structures (CO-FPNs) with tunable water pollutants-gas-solid (WGS) triple-phase interfaces that enhance oxygen enrichment and reactive oxygen species (ROS) production.
View Article and Find Full Text PDFLangmuir
November 2024
Wide Range Flight Engineering Science and Applications Center, Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190, China.
The wetting transition behaviors of polymeric droplets on microcavity surfaces are familiar and play a vital role in micromanufacturing, microfluidics, and printing industries. Despite previous research indicating that microcavity surfaces can precisely control the droplet wetting state, the understanding of the complex effects of droplet spreading, surface morphology, and property of polymeric droplet on wetting transitions remains incomplete. The air-liquid interfaces (ALIs) typically arise from the entrapped air beneath the droplet on microcavity surfaces, adopting a metastable wetting state caused by either bubble escape or dissolution.
View Article and Find Full Text PDFJ Chem Phys
November 2024
Institute of Nanotechnology, Karlsruhe Institute of Technology, Hermann-von-Helmholtz Pl. 1, 76344 Eggenstein-Leopoldshafen, Germany.
Variations from equilibrium Young's angle, known as contact angle hysteresis (CAH), are frequently observed upon droplet deposition on a solid surface. This ubiquitous phenomenon indicates the presence of multiple local surface energy minima for the sessile droplet. Previous research primarily explains CAH via considering macroscopic roughness, such as topographical defects, which alter the effective interfacial energy between the fluid phase and the solid phase, thereby shifting the global surface energy minimum.
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