The physico-chemical absorption characteristics of ammonium-N for 10 soils from 5 profiles in York, UK, show its high potential mobility in N deposition-impacted, unfertilized, permanent grassland soils. Substantial proportions of ammonium-N inputs were retained in the solution phase, indicating that ammonium translocation plays an important role in the N cycling in, and losses from, such soils. This conclusion was further supported by measuring the ammonium-N leaching from intact plant/soil microcosms. The ammonium-N absorption characteristics apparently varied with soil pH, depth and soil texture. It was concluded for the most acid soils especially that ammonium-N leached from litter horizons could be seriously limiting the capacity of underlying soils to retain ammonium. Contrary to common opinion, more attention therefore needs to be paid to ammonium leaching and its potential role in biogeochemical N cycling in semi-natural soil systems subject to atmospheric pollution.
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http://dx.doi.org/10.1016/j.envpol.2008.11.041 | DOI Listing |
Spectrochim Acta A Mol Biomol Spectrosc
December 2024
Intelligent Equipment Research Center, Beijing Academy of Agriculture and Forestry Sciences, Beijing 100097, China. Electronic address:
Gender identification of chick embryos at the early stages of incubation is of significant importance to poultry industry. Existing studies showed reproductive hormone concentrations are associated with gender of chick embryos. Accurate detection of reproductive hormone concentration can assist in gender identification.
View Article and Find Full Text PDFDiscov Nano
January 2025
Materials Science Innovation and Modelling (MaSIM) Research Focus Area, Faculty of Natural and Agricultural Sciences, North-West University, Mafikeng Campus, Private Bag X2046, Mmabatho, 2735, South Africa.
Hybrid wastewater treatment systems offer viable solutions to enhance the removal of complicated contaminants from aqueous system. This innovation has opened new avenues for advanced wastewater treatment processes. Herein, a novel TiO-ZnO functionalized coal fly ash-based ceramic membrane was fabricated by utilizing a combined pressing and sintering method.
View Article and Find Full Text PDFInorg Chem
January 2025
School of Chemistry and Chemical Engineering, Nanchang University, Nanchang 330031, P. R. China.
Organic-inorganic hybrid lead halides have been extensively studied due to their outstanding physical properties and diverse compositional elements. However, environmentally benign tin-based hybrids with remarkable flexibility in bandgap engineering have been less investigated. Herein, we report the successful design and synthesis of three tin-based organic-inorganic hybrid compounds through precise molecular modification: [Me(i-Pr)N][SnBr] (), [MeCHCl(i-Pr)N][SnBr] (), and [MeCHBr(i-Pr-Br)N][SnBr] ().
View Article and Find Full Text PDFSmall Methods
January 2025
Department of Chemical Engineering, National Taiwan University of Science and Technology, Taipei, 10607, Taiwan.
Electrochemical water splitting is a pivotal process for sustainable hydrogen energy production, relying on efficient hydrogen evolution reaction (HER) catalysts, particularly in acidic environments, where both high activity and durability are crucial. Despite the favorable kinetics of platinum (Pt)-based materials, their performance is hindered under harsh conditions, driving the search for alternatives. Due to their unique structural characteristic, Prussian blue analogs (PBAs) emerge as attractive candidates for designing efficient HER electrocatalysts.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Department of Chemistry, Laboratory of Advanced Materials, State Key Laboratory of Molecular Engineering of Polymers, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China.
Optical imaging in the second near-infrared window (NIR-II, 1000-1700 nm) holds great promise for biomedical detection due to reduced tissue scattering and autofluorescence. However, the rational design of NIR-II probes with superior excitation wavelengths to balance the effects of tissue scattering and water absorption remains a great challenge. To address this issue, here we developed a series of Ho-sensitized lanthanide (Ln) nanocrystals (NaYF: Ho, Ln@NaYF) excited at 1143 nm, featuring tunable emissions ranging from 1000 to 2200 nm for bioimaging.
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