The transition temperature T{C} approximately 26 K of the recently discovered superconductor LaFeAsO1-xFx is extremely sensitive to the lanthanide ion, reaching 55 K for the Sm containing oxypnictides. Therefore, it is important to determine how the moment on the lanthanide affects the overall magnetism in these systems. Here we report a neutron diffraction study of the Nd oxypnictides. Long-ranged antiferromagnetic order is apparent in NdFeAsO below 1.96 K. Rietveld refinement shows that both Fe and Nd magnetic ordering are required to describe the observed data with the staggered moment 1.55(4)micro{B}/Nd and 0.9(1)micro{B}/Fe at 0.3 K. The other structural properties such as the tetragonal-orthorhombic distortion are found to be very similar to those in LaFeAsO. Neither the magnetic ordering nor the structural distortion occur in the superconducting sample NdFeAsO0.80F0.20 at any temperatures down to 1.5 K.
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http://dx.doi.org/10.1103/PhysRevLett.101.257002 | DOI Listing |
Acta Crystallogr B Struct Sci Cryst Eng Mater
February 2025
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russian Federation.
The crystal structures and hyperfine magnetic parameters of EuFe(BO) and mixed EuLaFe(BO) were studied over a wide temperature range in order to analyze correlations of the structural and magnetic features and the phase transitions in multiferroic compounds of the rare-earth iron borate family. The chemical compositions of the crystals are reported from X-ray fluorescence analysis. The crystal structures of EuFe(BO) and EuLaFe(BO) were determined using single-crystal X-ray diffraction in the temperature range 25-500 K.
View Article and Find Full Text PDFJ Phys Condens Matter
January 2025
Department of Chemistry, Indian Institute of Technology Delhi, Indian Institute of Technology Delhi, Hauz Khas, New delhi, New Delhi, Delhi, 110016, INDIA.
We report the detailed investigation of the magnetic, transport, and magnetocaloric effects of GdS- bSe by magnetic susceptibility χ(T ), isothermal magnetization M (H), resistivity ρ(T, H), and heat capacity Cp(T ) measurements, crystallizing in the ZrSiS-type tetragonal crystal system with space group P 4/nmm. Temperature-dependent magnetic susceptibility measurements revealed long-range antiferromagnetic ordering with two additional magnetic anomalies below N´eel temperature (TN ≈ 8.6 K), corroborated through magnetocaloric and specific heat studies.
View Article and Find Full Text PDFAdv Mater
January 2025
Department of Materials Science and Engineering, Yonsei University, Seoul, 03722, Republic of Korea.
Interstitial quasi-atomic electrons (IQEs) in the quantized energy levels of positively charged cavities possess a substantial own magnetic moment and control the magnetism of crystalline electrides depending on the interaction with surrounding cations. However, weak spin-orbit coupling and gentle exchange interaction restricted by the IQEs preclude a large magnetic anisotropic, remaining a challenge for a hard magnetism. It is reported that 2D [ReC]·2e electrides (Re = Er, Ho, Dy, and Tb) show the permanent magnetism in a ferrimagnetic ground state, mimicking the ferrites composed of magnetic sublattices with different spin polarizations.
View Article and Find Full Text PDFNature
January 2025
Max-Planck-Institut für Quantenoptik, Garching, Germany.
The relation between d-wave superconductivity and stripes is fundamental to the understanding of ordered phases in high-temperature cuprate superconductors. These phases can be strongly influenced by anisotropic couplings, leading to higher critical temperatures, as emphasized by the recent discovery of superconductivity in nickelates. Quantum simulators with ultracold atoms provide a versatile platform to engineer such couplings and to observe emergent structures in real space with single-particle resolution.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
December 2024
Hubei Key Laboratory of Optical Information and Pattern Recognition, Wuhan Institute of Technology, Wuhan 430205, China. Electronic address:
Two-dimensional antiferromagnetic materials have attracted wide attention in both performance and application, which are of great significance for spin valves and next-generation magnetic random access memory devices. The spin-phonon coupling effect plays a crucial role in magnon dynamics. However, there is still a lack of research on the spin-phonon coupling effect of two-dimensional antiferromagnetic flakes.
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