The in-plane magnetic penetration depth lambda ab in optimally doped (BiPb)2(SrLa)2CuO6+delta (OP Bi2201) was studied by means of muon-spin rotation. The measurements of lambda ab(-2)(T) are inconsistent with a simple model of a d-wave order parameter and a uniform quasiparticle weight around the Fermi surface. The data are well described assuming the angular gap symmetry obtained in ARPES experiments [Phys. Rev. Lett. 98, 267004 (2007)], which suggest that the superconducting gap in OP Bi2201 exists only in segments of the Fermi surface near the nodes. The remaining parts of the Fermi surface, which are strongly affected by the pseudogap state, do not contribute significantly to the superconducting condensate.
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http://dx.doi.org/10.1103/PhysRevLett.101.227002 | DOI Listing |
Anal Chem
December 2024
Phenikaa University Nano Institute (PHENA), Phenikaa University, Hanoi 12116, Vietnam.
Surface-enhanced Raman spectroscopy (SERS) is a powerful analytical technique, yet it faces challenges with certain probe molecules exhibiting weak or inactive signals, limiting their applicability. In a recent study, we investigated this phenomenon using a set of four probe molecules─chloramphenicol (CAP), 4-nitrophenol (4-NP), amoxicillin (AMX), and furazolidone (FZD)─deposited on Ag-based nanostructured SERS substrates. Despite being measured under identical conditions, CAP and 4-NP exhibited SERS activity, while AMX and FZD did not.
View Article and Find Full Text PDFAdv Mater
December 2024
Department of Physics, Indian Institute of Science Education and Research Bhopal, Bhopal, Madhya Pradesh, 462066, India.
Weyl semimetals are a novel class of topological materials with unique electronic structures and distinct properties. HfRhGe stands out as a noncentrosymmetric Weyl semimetal with unconventional superconducting characteristics. Using muon-spin rotation and relaxation (µSR) spectroscopy and thermodynamic measurements, a fully gapped superconducting state is identified in HfRhGe that breaks time-reversal symmetry at the superconducting transition.
View Article and Find Full Text PDFJ Am Chem Soc
December 2024
Department of Chemical Engineering, Virginia Tech, Blacksburg, Virginia 24061, United States.
The decomposition of ozone on supported manganese oxide catalysts, studied here, exemplifies reactions involving electron transfer. In situ extended X-ray absorption fine-structure spectra (Mn K-edge) on in situ treated samples show that the supported phase in MnO/SiO resembles MnO while that in MnO/AlO samples resembles MnO. In situ Raman spectroscopy shows the involvement of a common peroxide surface species.
View Article and Find Full Text PDFAdv Sci (Weinh)
December 2024
Shenzhen Key Laboratory of Advanced Thin Films and Applications, College of Physics and optoelectronic engineering, Shenzhen University, Shenzhen, 518060, P. R. China.
Crystalline thermoelectric materials, especially SnSe crystals, have emerged as promising candidates for power generation and electronic cooling. In this study, significant enhancement in ZT is achieved through the combined effects of lattice distortions and band convergence in multiple electronic valence bands. Density functional theory (DFT) calculations demonstrate that cation vacancies together with Pb substitutional doping promote the band convergence and increase the density of states (DOS) near the Fermi surface of SnSe, leading to a notable increase in the Seebeck coefficient (S).
View Article and Find Full Text PDFAdv Sci (Weinh)
December 2024
Department of Physics, University of Basel, Klingelbergstrasse 82, Basel, 4056, Switzerland.
Many-body interactions in metal-organic frameworks (MOFs) are fundamental for emergent quantum physics. Unlike their solution counterpart, magnetization at surfaces in low-dimensional analogues is strongly influenced by magnetic anisotropy (MA) induced by the substrate and still not well understood. Here, on-surface coordination chemistry is used to synthesize on Ag(111) and superconducting Pb(111) an iron-based spin chain by using pyrene-4,5,9,10-tetraone (PTO) precursors as ligands.
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