We found that dodecatungstophosphoric acid (H(3)PW(12)O40), samarium and ruthenium(III) chloride act as efficient catalysts for synthesis of unsaturated 2-phenyl-5(4H)oxazolone derivatives under solvent-free conditions. The key features of the reported protocols are short reaction times, high yields of products, ambient conditions and simple workup.
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http://dx.doi.org/10.3390/molecules13123246 | DOI Listing |
Mater Sci Eng C Mater Biol Appl
November 2018
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, National Analytical Research Center of Electrochemistry and Spectroscopy, Changchun, 130022, People's Republic of China. Electronic address:
A series of cerium-exchanged dodecatungstophosphates CeHPWO (CeHPW, x = 0.4, 0.6, 0.
View Article and Find Full Text PDFPhys Chem Chem Phys
June 2015
Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8550, Japan.
Ag(+)-exchanged zeolites exhibit unique catalytic properties caused by the combination of their redox and acidic properties. Partial reduction of Ag(+) ions in zeolites with hydrogen leads to the formation of acidic protons and silver metal particles, which can be observed using X-ray powder diffraction patterns (XRD). By simply evacuating hydrogen from the system, the silver metal particles are returned back to Ag(+) ions and at the same time, acidic protons are eliminated.
View Article and Find Full Text PDFMolecules
December 2008
Department of Chemistry, Shahid Bahonar University of Kerman, Kerman, Iran.
We found that dodecatungstophosphoric acid (H(3)PW(12)O40), samarium and ruthenium(III) chloride act as efficient catalysts for synthesis of unsaturated 2-phenyl-5(4H)oxazolone derivatives under solvent-free conditions. The key features of the reported protocols are short reaction times, high yields of products, ambient conditions and simple workup.
View Article and Find Full Text PDFAnal Chem
May 2004
Department of Chemistry, University of Warsaw, Pasteura 1, PL-02-093 Warsaw, Poland.
A novel electroanalytical approach is proposed here, and it is demonstrated with the direct and simultaneous determination of two unknowns: the concentration of redox sites and the apparent diffusion coefficient for charge propagation in a single crystal of dodecatungstophosphoric acid. This Keggin-type polyoxometalate serves as a model bulk redox conducting inorganic material for solid-state voltammetry. The system has been investigated using an ultramicrodisk working electrode in the absence of external liquid supporting electrolyte.
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