Unprecedented self-catenated eight-connected network based on novel azide-bridged tetramanganese(II) clusters.

Inorg Chem

Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China.

Published: February 2009

The combination of the azide bridge and a neutral inner-salt-type dicarboxylate ligand leads to a three-dimensional coordination framework that contains unprecedented azide-bridged tetramanganese(II) clusters and defines a novel self-catenated, eight-connected net of 4(16) x 6(12) topology.

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Source
http://dx.doi.org/10.1021/ic801968xDOI Listing

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