Thermal transport and breakdown in Joule-heated GaN nanowires is investigated using a combination of microphotoluminescence and in situ TEM characterization. The thermal conductivity of the nanowires is estimated to be <80 W/m.K, which is substantially below the bulk GaN value. Catastrophic breakdown in individual nanowires is observed to occur at a maximum temperature of approximately 1000 K, and nanowire morphology near the breakdown region indicates that failure occurs via thermal decomposition, a conclusion that is validated by in situ TEM images obtained during the failure process.
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http://dx.doi.org/10.1021/nl802840w | DOI Listing |
ACS Appl Mater Interfaces
January 2025
College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, P. R. China.
Thermoelectric technology enables the direct and reversible conversion of heat into electrical energy without air pollution. Herein, the stability, electronic structure, and thermoelectric properties of methoxy-functionalized MC(OMe) (M = Sc, Ti, V, Cr, Y, Zr, Nb, Mo, Hf, Ta, and W) were systematically investigated using first-principles calculations and semiclassical Boltzmann transport theory. All MXenes, except those with M = Cr, Mo, and W, can be synthesized by substituting Cl- and Br-functionalized MXenes with deprotonated methanol, with stability governed by the M-O bond strength.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
Department of Physics, University of Washington, Seattle, Washington 98195, USA.
We study hydrodynamic thermal transport in high-mobility two-dimensional electron systems placed in an in-plane magnetic field and identify a new mechanism of thermal magnetotransport. This mechanism is caused by drag between the electron populations with opposite spin polarization, which arises in the presence of a hydrodynamic flow of heat. In high mobility systems, spin drag results in strong thermal magnetoresistance, which becomes of the order of 100% at relatively small spin polarization of the electron liquid.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
Center for Phononics and Thermal Energy Science, School of Physics Science and Engineering, Tongji University, Shanghai 20092, China.
In contrast to normal diffusion processes, thermal conduction in one-dimensional systems is anomalous. The thermal conductivity is found to vary with the length as κ∼L^{α}(α>0), but there is a long-standing debate on the value α. Here, we present a canonical example of this behavior in polymer-grafted spherical nanoparticle (GNP) melts at fixed grafting density and nanoparticle radius.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
EPFL: Ecole Polytechnique Federale de Lausanne, Department of Chemistry, Rue de Industries 17, 1050, Sion, SWITZERLAND.
Li-TFSI/t-BP is the most widely utilized p-dopant for hole-transporting materials (HTMs) in state-of-the-art perovskite solar cells (PSCs). However, its nonuniformity of doping, along with the hygroscopicity and migration of dopants, results in the devices that exhibit limited stability and performance. This study reports the use of a spherical anion of the p-dopant, regulated by its radius and shape, as an alternative to the linear TFSI- anion.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Mechanical Engineering, College of Engineering, University of Ha'il, 81451, Ha'il City, Saudi Arabia.
Non-Newtonian fluids are also widely used in a variety of scientific, engineering, and industrial domains, including the petroleum sector and polymer technologies. They are vital in the development of drag-reducing agents, damping and braking systems, food manufacturing, personal protective equipment, and the printing industry. Fluid movement and transport via porous materials draw a lot of attention; they are important in science and technology.
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