Massive aligned carbon nanotubes hold great potential but also face significant integration/assembly challenges for future beyond-silicon nanoelectronics. We report a wafer-scale processing of aligned nanotube devices and integrated circuits, including progress on essential technological components such as wafer-scale synthesis of aligned nanotubes, wafer-scale transfer of nanotubes to silicon wafers, metallic nanotube removal and chemical doping, and defect-tolerant integrated nanotube circuits. We have achieved synthesis of massive aligned nanotubes on complete 4 in. quartz and sapphire substrates, which were then transferred to 4 in. Si/SiO(2) wafers. CMOS analogous fabrication was performed to yield transistors and circuits with features down to 0.5 mum, with high current density approximately 20 muA/mum and good on/off ratios. In addition, chemical doping has been used to build fully integrated complementary inverter with a gain approximately 5, and a defect-tolerant design has been employed for NAND and NOR gates. This full-wafer approach could serve as a critical foundation for future integrated nanotube circuits.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1021/nl802756u | DOI Listing |
J Chem Theory Comput
January 2025
Department of Chemistry and Biochemistry, The University of Texas at El Paso, El Paso, Texas 79968, United States.
In this work, we describe a computational tool designed to determine the local dielectric constants (ε) of charge-neutral heterogeneous systems by analyzing dipole moment fluctuations from molecular dynamics (MD) trajectories. Unlike conventional methods, our tool can calculate dielectric constants for dynamically evolving selections of molecules within a defined region of space, rather than for fixed sets of molecules. We validated our approach by computing the dielectric constants of TIP3P water nanospheres, achieving results consistent with literature values for bulk water.
View Article and Find Full Text PDFPolymers (Basel)
December 2024
Green Technology Group, Faculty of Science, Alexandria University, Alexandria 21511, Egypt.
Plastic waste (PW) presents a significant environmental challenge due to its persistent accumulation and harmful effects on ecosystems. According to the United Nations Environment Program (UNEP), global plastic production in 2024 is estimated to reach approximately 500 million tons. Without effective intervention, most of this plastic is expected to become waste, potentially resulting in billions of tons of accumulated PW by 2060.
View Article and Find Full Text PDFSci Adv
January 2025
Department of Mechanical Engineering, University of Delaware, Newark, DE 19716, USA.
Nat Commun
January 2025
School of Materials Science and Engineering, Peking University, Beijing, China.
In the realm of modern materials science, horizontally aligned carbon nanotube arrays stand as promising materials for the development of next-generation integrated circuits. However, their large-scale integration has been impeded by the constraints of current fabrication techniques, which struggle to achieve the necessary uniformity, density, and size control of carbon nanotube arrays. Overcoming this challenge necessitates a significant shift in fabrication approaches.
View Article and Find Full Text PDFSmall
December 2024
Department of Chemistry & Chemical Biology and the Brockhouse Institute for Materials Research, McMaster University, 1280 Main St. W., Hamilton, ON, L8S 4M1, Canada.
Flexible sensors have garnered significant interest for their potential to monitor human activities and provide valuable feedback for healthcare purposes. Single-walled carbon nanotubes (SWNTs) are promising materials for these applications but suffer from issues of poor purity and solubility. Dispersing SWNTs with conjugated polymers (CPs) enhances solution processability, yet the polymer sidechains can insulate the SWNTs, limiting the sensor's operating voltage.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!