A series of bis(gallyl) lanthanide(ii) complexes, [Ln(II){Ga[(ArNCH)(2)]}(2)(tmeda)(2)] (Ln = Sm, Eu or Yb; Ar = C(6)H(3)Pr(i)(2)-2,6), and a gallyl thulium(iii) compound, [Tm(III){Ga[(ArNCH)(2)]}{(ArNCH)(2)}(tmeda)], have been prepared; the first structural studies of Ga-Tm and Ga-Sm bonded complexes are described.
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http://dx.doi.org/10.1039/b817933f | DOI Listing |
Chem Commun (Camb)
January 2009
School of Chemistry, Monash University, Melbourne, PO Box 23, Victoria, 3800, Australia.
A series of bis(gallyl) lanthanide(ii) complexes, [Ln(II){Ga[(ArNCH)(2)]}(2)(tmeda)(2)] (Ln = Sm, Eu or Yb; Ar = C(6)H(3)Pr(i)(2)-2,6), and a gallyl thulium(iii) compound, [Tm(III){Ga[(ArNCH)(2)]}{(ArNCH)(2)}(tmeda)], have been prepared; the first structural studies of Ga-Tm and Ga-Sm bonded complexes are described.
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