Gallyl lanthanide complexes containing unsupported Ln-Ga (Ln = Sm, Eu, Yb or Tm) bonds.

Chem Commun (Camb)

School of Chemistry, Monash University, Melbourne, PO Box 23, Victoria, 3800, Australia.

Published: January 2009

A series of bis(gallyl) lanthanide(ii) complexes, [Ln(II){Ga[(ArNCH)(2)]}(2)(tmeda)(2)] (Ln = Sm, Eu or Yb; Ar = C(6)H(3)Pr(i)(2)-2,6), and a gallyl thulium(iii) compound, [Tm(III){Ga[(ArNCH)(2)]}{(ArNCH)(2)}(tmeda)], have been prepared; the first structural studies of Ga-Tm and Ga-Sm bonded complexes are described.

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http://dx.doi.org/10.1039/b817933fDOI Listing

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Gallyl lanthanide complexes containing unsupported Ln-Ga (Ln = Sm, Eu, Yb or Tm) bonds.

Chem Commun (Camb)

January 2009

School of Chemistry, Monash University, Melbourne, PO Box 23, Victoria, 3800, Australia.

A series of bis(gallyl) lanthanide(ii) complexes, [Ln(II){Ga[(ArNCH)(2)]}(2)(tmeda)(2)] (Ln = Sm, Eu or Yb; Ar = C(6)H(3)Pr(i)(2)-2,6), and a gallyl thulium(iii) compound, [Tm(III){Ga[(ArNCH)(2)]}{(ArNCH)(2)}(tmeda)], have been prepared; the first structural studies of Ga-Tm and Ga-Sm bonded complexes are described.

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