AI Article Synopsis
- The reaction of dichlorodiphenylsilane with a specific Schiff base ligand forms a complex silicon compound known for its large and intricate structure.
- The compound, detailed with its long chemical name, features a centrosymmetric macrocycle that incorporates multiple chemical elements such as carbon, nitrogen, oxygen, and silicon.
- Its crystal structure includes interactions with chloroform molecules, suggesting potential applications in molecular recognition and nanostructure development.
Article Abstract
The reaction of dichlorodiphenylsilane with a polydentate Schiff base ligand derived from pyridoxal and 2-hydroxyaniline yields the macrocyclic centrosymmetric silicon compound 9,27-dimethyl-3,3,21,21-tetraphenyl-2,4,20,22-tetraoxa-8,13,26,31-tetraaza-3,21-disilapentacyclo[30.4.0.0(6,11).0(14,19).0(24,29)]hexatrideca-1(32),6,8,10,12,14,16,18,24,26,28,30,33,35-tetradecaene-10,28-diol chloroform tetrasolvate, C(52)H(44)N(4)O(6)Si(2) x 4CHCl(3). The asymmetric unit contains half of the macrocycle and two molecules of chloroform, with C-H...O and C-H...N contacts binding the two guests to the host in the crystal structure. This macrocyclic silicon compound represents a promising host for molecular-recognition processes and for the construction of nanostructures.
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| http://dx.doi.org/10.1107/S0108270108036238 | DOI Listing |
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