The experimental study of explosive combustion of LPG (liquefied petroleum gas)-air mixtures at ambient initial temperature was performed in two closed vessels with central ignition, at various total initial pressures within 0.3-1.3bar and various fuel/air ratios, within the flammability limits. The transient pressure-time records were used to determine several explosion characteristics of LPG-air: the peak explosion pressure, the explosion time (the time necessary to reach the peak pressure), the maximum rate of pressure rise and the severity factor. All explosion parameters are strongly dependent on initial pressure of fuel-air mixture and on fuel/air ratio. The explosion characteristics of LPG-air mixtures are discussed in comparison with data referring to the main components of LPG: propane and butane, obtained in identical conditions.
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http://dx.doi.org/10.1016/j.jhazmat.2008.10.082 | DOI Listing |
Astrobiology
January 2025
NASA Goddard Space Flight Center, Greenbelt, Maryland, USA.
Meteoritic impacts on planetary surfaces deliver a significant amount of energy that can produce prebiotic organic compounds such as cyanides, which may be a key step to the formation of biomolecules. To study the chemical processes of impact-induced organic synthesis, we simulated the physicochemical processes of hypervelocity impacts (HVI) in experiments with both high-speed C projectiles and laser ablation. In the first approach, a C beam was accelerated to collide with ammonium nitrate (NHNO) to reproduce the shock process and plume generation of meteoritic impacts on nitrogen-rich planetary surfaces.
View Article and Find Full Text PDFBackground: Dengue, chikungunya, and Zika are mosquito-borne diseases of major human concern. Differential diagnosis is complicated in children and adolescents by their overlapping clinical features (signs, symptoms, and complete blood count results). Few studies have directly compared the three diseases.
View Article and Find Full Text PDFACS Omega
January 2025
College of Safety Science and Engineering, Liaoning Technical University, Fuxin 123000, Liaoning, China.
To minimize the number of casualties due to poisoning in coal mine gas explosions, the migration characteristics of harmful hot gas groups in the mine ventilation system following an explosion were analyzed. Through pipeline experiments, initial CO concentrations and residual temperatures after gas explosions were determined and used as key simulation parameters. Simulations were performed using the TF1M(3D) software based on the case of the gas explosion at the Tunlan Mine.
View Article and Find Full Text PDFSmall
January 2025
NanoScience Technology Center, Department of Materials Science and Engineering, Department of Chemistry, Renewable Energy and Chemical Transformation Cluster, The Stephen W. Hawking Center for Microgravity Research and Education, University of Central Florida, Orlando, FL, 32826, USA.
Since the explosive growth of state-of-the-art electronics and devices raises concerns about electromagnetic pollution, exploring novel and efficient electromagnetic interference (EMI) shielding materials is desirable and crucial. TiCT MXenes hold significant EMI shielding potential due to their inherent characteristics, including lightweight, metal-like conductivities, unique layered structure, and facile processing. Nonetheless, it remains challenging to fabricate TiCT MXenes-based EMI shielding materials with efficient shielding capability and low reflection.
View Article and Find Full Text PDFJ Mol Model
January 2025
School of Safety Science and Engineering, Nanjing University of Science and Technology, Nanjing, 210094, China.
Context: 3,4-Bis(3-nitrofurazan-4-yl) furoxan (DNTF) is a typical low-melting-point, high-energy-density compound that can serve as a cast carrier explosive. Therefore, understanding the safety of DNTF under different casting processes is of great significance for its efficient application. This study employed molecular dynamics simulations to investigate the effects of temperature and pressure on the self-diffusion characteristics and mechanical sensitivity of DNTF.
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