While chiral materials are common, few are known that integrate molecular chirality, absolute helicity, and 3-D intrinsically chiral topological nets in one material. Such multihomochiral features may lead to enhanced chiral recognition processes that are important for enantioselective catalysis or separation. Reported here are a series of 3-D open-framework materials with unusual integration of various homochiral and homohelical features, even in the bulk sample.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2782683 | PMC |
| http://dx.doi.org/10.1021/ja8075692 | DOI Listing |
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