Formation of an epoxide before 9-membered ring cyclization and SmI2 mediated reductive olefination in the presence of the epoxide successfully produced the epoxybicyclo[7.3.0]dodecadienediyne core of the kedarcidin chromophore.
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Secure route to the epoxybicyclo[7.3.0]dodecadienediyne core of the kedarcidin chromophore.
Chem Commun (Camb)
December 2008
Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan.
Formation of an epoxide before 9-membered ring cyclization and SmI2 mediated reductive olefination in the presence of the epoxide successfully produced the epoxybicyclo[7.3.0]dodecadienediyne core of the kedarcidin chromophore.
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