Hierarchical organization of 'systems within systems' is an apparent characteristic of nature. For many biotic and abiotic systems it is known how the nested structural and functional order builds up, yet the general principle why matter evolves to hierarchies has remained unfamiliar to many. We clarify that increasingly larger integrated systems result from the quest to decrease free energy according to the 2nd law of thermodynamics. The argumentation is based on the recently derived equation of motion for natural processes. Hierarchically organized energy transduction machinery emerges naturally when it provides increased rates of energy dispersal. Likewise, a hierarchical system will dismantle into its constituents when they as independent systems will provide higher rates of entropy increase. Since energy flows via interactions, decreasing strengths of interactions over increasingly larges lengths scales mark natural boundaries for nested integrated systems.
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http://dx.doi.org/10.1016/j.biosystems.2008.10.008 | DOI Listing |
Chem Sci
December 2024
Department of Chemistry, Biology and Biotechnology, University of Perugia Via Elce di Sotto, 8 06123 Perugia Italy
The majority of enantioselective organocatalytic reactions occur in apolar or weakly polar organic solvents. Nevertheless, the influence of solute-solvent van der Waals forces on the relative kinetics of competitive pathways remains poorly understood. In this study, we provide a first insight into the nature and strength of these interactions at the transition state level using advanced computational tools, shedding light into their influence on the selectivity.
View Article and Find Full Text PDFNanoscale Adv
December 2024
Department of Chemical Engineering, Sirjan University of Technology Sirjan Iran https://scholar.google.com/citations?user=N6z-rHsAAAAJ&hl=en.
The potential applicability of the C nanocage and its boron nitride-doped analogs (CBN and CBN) as pyrazinamide (PA) carriers was investigated using density functional theory. Geometry optimization and energy calculations were performed using the B3LYP functional and 6-31G(d) basis set. Besides, dispersion-corrected interaction energies were calculated at CAM (Coulomb attenuated method)-B3LYP/6-31G(d,p) and M06-2X/6-31G(d,p) levels of theory.
View Article and Find Full Text PDFACS Mater Au
January 2025
Department of Electrical and Electronic Engineering, Kyushu Institute of Technology, 1-1 Sensuicho, Tobataku, Kitakyushu, Fukuoka 804-8550, Japan.
Ionic gels (IGs), ionic liquids (ILs) dispersed in polymers, exhibit extremely low vapor pressure, electrochemical and thermal stability, and excellent mechanical characteristics; therefore, they are used for fabricating stretchable sensors, electrochemical transistors, and energy storage devices. Although such characteristics are promising for flexible and stretchable electronics, the mechanical stress-induced ruptured covalent bonds forming polymer networks cannot recover owing to the irreversible interaction between the bonds. Physical cross-linking via noncovalent bonds enables the interaction of polymers and ILs to form supramolecular IGs (SIGs), which exhibit favorable characteristics for wearable devices that conventional IGs with noncovalent bonds cannot achieve.
View Article and Find Full Text PDFHeliyon
January 2025
Department of Pharmaceutical Science, Faculty of Pharmacy, Umm Al-Qura University, Makkah, P.O. Box 751, Saudi Arabia.
This study presents the synthesis and application of water-ball (sodium polyacrylate) stabilized zero-valent iron nanoparticles (wb@Fe) for the eco-friendly degradation of Methyl Orange (MO). The nanoparticles were prepared using a chemical reduction method using NaBH. Characterization techniques including Field Emission Scanning Electron Microscopy (FESEM), Energy Dispersive X-ray Spectroscopy (EDS), Fourier Transform Infrared Spectroscopy (FTIR), X-ray Photoelectron Spectroscopy (XPS), and X-ray Diffraction (XRD) were employed to analyze the morphology, elemental composition, valent state and crystallinity of the nanoparticles.
View Article and Find Full Text PDFHeliyon
January 2025
Department of Food Engineering Technologies, Faculty of Technical Engineering, Aleppo University, Syria.
The objective of this study was to extract and characterize nanocellulose from sesame husks, which are typically discarded as waste by sesame processing facilities. However, these husks are rich in cellulose, presenting a valuable potential source for nanocellulose. Sesame husk cellulose (SHC) was initially isolated through a multi-step process that removed oil, hemicellulose, and lignin.
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