A novel perylenetetracarboxylic diimide molecule (2PDI-TAZ), which contains two perylenetetracarboxylic diimide (PDI) attached to a melamine headgroup, was designed and synthesized. Supramolecular self-assemblies were studied in Langmuir and Langmuir-Blodgett films. Surface pressure-area isotherm measurements and the spectroscopic studies indicate that the 2PDI-TAZ molecules adopted a face-to-face configuration and edge-on orientation in Langmuir or the multilayer LB films. The presence of the barbituric acid in subphase change the hydrophilicity of 2PDI-TAZ due to the hydrogen bonding between melamine and barbituric acid, which has been revealed by the pi-A isotherms and the FT-IR spectra. Transmission electron microscopy images of the LB films deposited from the barbituric acid solution revealed uniform nanowire morphology while the X-ray diffraction studies indicate that the molecules in the solid film packed with high order. The strong excimer emission of 2PDI-TAZ in LB films suggests enforced face-to-face configuration for the PDI unites in LB films in relative to that in solution.
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http://dx.doi.org/10.1016/j.jcis.2008.10.074 | DOI Listing |
J Chem Phys
October 2024
Academic Assembly Faculty of Engineering, University of Toyama, Toyama 930-8555, Japan.
Molecular dynamics simulations were performed to investigate the interfacial structure of the N,N'-di-n-alkyl-3,4,9,10-perylenetetracarboxylic diimide (PTCDI)/rubrene interface, which represents the donor/acceptor interface in new types of organic light-emission diodes. In particular, the interfacial structure was examined for different alkyl chain lengths of PTCDI (Cn-PTCDI) at n = 4, 8, and 13, in order to elucidate the observed maximum charge transfer efficiency at the C8-PTCDI/rubrene interface in a recent experiment. The results revealed that the molecular conformation of the acceptor (Cn-PTCDI) molecules at the interface undergoes changes depending on the alkyl chain length when interacting with the rubrene molecule.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
September 2024
School of Chemistry and Chemical Engineering, Ministry of Education, Guangzhou University, Guangzhou 510006.
Talanta
October 2024
Graduate School of Environmental Studies, Tohoku University, 6-6-11 Aramaki Aoba, Aoba, Sendai, Miyagi, 980-8579, Japan; Graduate School of Engineering, Tohoku University, 6-6-11 Aramaki Aoba, Aoba, Sendai, Miyagi, 980-8579, Japan. Electronic address:
Bipolar electrochemical microscopy (BEM), which visualizes the concentration distribution of molecular species in biological systems by electrochemiluminescence (ECL), is expected to be applied to the high-spatiotemporal-resolution imaging of biomolecules, enabling the analysis of cellular functions. In the past, the molecular species that could be imaged by BEM were generally restricted to oxidized molecules due to the limitation derived from the ECL mechanism of the luminophore. Recently, the imaging of dopamine (DA), a reduced molecule, was achieved using Ru (bpy)/glutathione disulfide (GSSG) as a cathodic luminophore.
View Article and Find Full Text PDFChem Commun (Camb)
July 2024
Physical Sciences Division, Pacific Northwest National Laboratory, Richland, WA 99352, USA.
Molecules
May 2024
Department of Sciences and Informatics, Muroran Institute of Technology, Mizumoto-cho 27-1, Muroran 050-8585, Hokkaido, Japan.
Perylenetetracarboxylic diimide (PTCDI) is an n-type organic semiconductor molecule that has been widely utilized in numerous applications such as photocatalysis and field-effect transistors. Polarizability and dipole moment, which are inherent properties of molecules, are important parameters that determine their responses to external electric and optical fields, physical properties, and reactivity. These parameters are fundamentally important for the design of innovative materials.
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