A study of microwave-induced and standard thermal Overman rearrangement of selected allylic trichloroacetimidates 1a-1f, 6-8 to the corresponding acetamides 2a-2f, 9-11 is reported. The microwave-assisted rearrangement of trifluoroacetimidate 13 is also described. Using this methodology, an efficient access to versatile allylic trihaloacetamides building synthons was established.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6245460 | PMC |
| http://dx.doi.org/10.3390/molecules131102837 | DOI Listing |
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