A new stable chelating resin was synthesized by incorporating the bis(2-benzimidazolyl methyl)amine into Merrifield polymer through CN covalent bond and characterized by elemental analysis, IR and thermal study. The sorption capacity of the newly formed resin for Ag(I), Cu(II), Fe(III), Hg(II) and Pb(II) as a function of pH have been studied. The resin exhibits no affinity for alkali or alkaline earth metals. In column operation it has been observed that Ag(I) in trace quantities can be separated from different complex matrices and Hg(II) can be removed from the river water spiked with Hg(II) at usual pH of natural waters.

Download full-text PDF

Source
http://dx.doi.org/10.1016/j.talanta.2003.11.026DOI Listing

Publication Analysis

Top Keywords

chelating resin
8
resin bis2-benzimidazolylmethylamine
4
bis2-benzimidazolylmethylamine synthesis
4
synthesis metal-ion
4
metal-ion uptake
4
uptake properties
4
properties suitable
4
suitable analytical
4
analytical application
4
application stable
4

Similar Publications

Laser-induced fluorescence spectroscopy was used to detect mercury ions in aqueous solutions, in which CH-95 resin was used to chelate the ions to transform the liquid samples into solid ones. The experimental results showed that the fluorescence emission of the chelated solid-state samples excited by a low-power semiconductor laser at the wavelength of 447 nm was significantly enhanced due to the chelating reaction. The fluorescence intensity was proportional to the concentration of mercury ions with a linear correlation coefficient of = 0.

View Article and Find Full Text PDF

Dissolved Rare Earth Elements (REEs) concentrations have been widely used in geochemical studies due to their systematic changes in the environment, acting as tracers in various natural processes. In addition to the usefulness of naturally controlled chemical REE fractionations used in the ocean, the extraction and measurement procedures of seawater REEs using chelating resin and ICP-MS may also be subject to method-derived analytical fractionations, leading to potential misinterpretations. The bracketing standard and the Lu methods were compared to verify any fractionation or deviation associated with the analytical processes.

View Article and Find Full Text PDF

ANTIMICROBIAL ACTION OF A MODIFIED UNIVERSAL ADHESIVE: AN IN VITRO STUDY.

Georgian Med News

November 2024

2Department of Conservative Dentistry, College of Dentistry, University of Mosul, Iraq.

Background: Resin composites and dental adhesives are widely used to restore carious teeth. A relatively new category of the dental adhesives, the universal adhesives (UAs) is considered user friendly because of its simplicity to use and compatibility with any adhesive strategy. However, the adhesive interface created by these adhesives is highly susceptible to cracking after polymerization which in turn facilitates the initiation of secondary caries.

View Article and Find Full Text PDF

This study introduces a novel bilayer wound dressing that integrates a quaternized chitosan-polyacrylic acid (QCs-PAA) sponge as the top layer with electrospun nanofibers containing curcumin as the bottom layer. For the first time, QCs and PAA were combined in an 80:20 ratio through freeze-drying to form a porous sponge layer with ideal structural properties, including 83 ± 6 % porosity and pore diameters of 290 ± 12.5 μm.

View Article and Find Full Text PDF

Objectives: This study evaluates the effect of different irrigation solutions for postoperative pain in the regenerative endodontic treatments (RET) of necrotic teeth with open apex.

Materials And Methods: This study included necrotic, deeply carious lower molars of 42 patients. Access cavities of the teeth were opened and working lengths were measured at the first visit.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!