The analytical properties of 1-phenyl-1,2-propanedione-2-oxime thiosemi-carbazone (PPDOT) are described for the first time. The reagent gives colour reactions with copper(II) and nickel(II) in sodium acetate-acetic acid buffer medium. The copper complex shows maximum absorbance at 465 nm while the nickel complex at 395 nm. Therefore, these colour reactions have been advantageously used for the simultaneous spectrophotometric determination of copper(II) and nickel(II) in synthetic mixture and also in edible oils and seeds.
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http://dx.doi.org/10.1016/s0039-9140(02)00543-x | DOI Listing |
Chemphyschem
November 2024
University of Belgrade: Univerzitet u Beogradu, Faculty of Physical Chemistry, SERBIA.
Inorg Chem
November 2024
Department of Chemistry, University at Buffalo, The State University of New York, Buffalo, New York14260, United States.
Herein, we report the reaction between four 1,2-dibromoxylenes and two tetra-3-pyridylporphyrins for the formation of a cofacial porphyrin core spanned by dipyridinium xylene moieties. The metal-free organic nanocage (oNC) was synthesized in one twenty-four h step at a gram-scale with a 91.5% yield.
View Article and Find Full Text PDFACS Omega
September 2024
Faculty of Chemistry, Warsaw University of Technology, Noakowskiego Street 3, 00-664 Warsaw, Poland.
The 1,3-dipolar cycloaddition reaction (click chemistry approach) was employed to create a hexa-ferrocenylated 1,3,5-triphenylbenzene derivative. Leveraging the presence of metal-chelating sites associated with 1,2,3-triazole moieties and 1,4-dinitrogen systems (ethylenediamine-like), as well as tridentate chelating sites (1,4,7-trinitrogen, diethylene triamine-like) systems, the application of this molecule as a chemosensor for divalent transition metal cations was investigated. The interactions were probed voltammetrically and spectrofluorimetrically against seven selected cations: iron(II) (Fe), cobalt(II) (Co), nickel(II) (Ni), copper(II) (Cu), zinc(II) (Zn), cadmium(II) (Cd), and manganese(II) (Mn).
View Article and Find Full Text PDFChem Asian J
December 2024
Institut für Anorganische Chemie und Strukturchemie, Universität Düsseldorf, Universitätsstr. 1, D-40225, Düsseldorf, Germany.
Reaction of the phenolate or naphthalen-2-olate based Schiff base ligands, (E)-1-((2-ethylphenylimino)methyl)phenol (HL1) or (E)-1-((2-ethylphenylimino)methyl)naphthalen-2-ol (HL2) with nickel(II) and copper(II) acetate provides the complexes bis[(E)-1-((2-ethylphenylimino)methyl)phenolato-ĸN,O]Ni/Cu(II), [Ni(L1)] (1) and [Cu(L1)] (2), or bis[(E)-1-((2-ethylphenylimino)methyl)naphthalen-2-olato-ĸN,O]Ni/Cu(II), [Ni(L2)] (3) and [Cu(L2)] (4), respectively. Single crystal X-ray structure determinations for 1, 3 and 4 reveal N,O-metal coordination of two chelating Schiff base ligands in a square-planar geometry. Powder X-ray diffractograms confirm the phase purity of the bulk microcrystalline samples.
View Article and Find Full Text PDFDalton Trans
September 2024
Department of Molecular Sciences, Swedish University of Agricultural Sciences, P.O. Box 7015, SE-750 07 Uppsala, Sweden.
The structures of nine hydrated metal ions in aqueous solution have been redetermined by large angle X-ray scattering to obtain experimental data of better quality than those reported 40-50 years ago. Accurate M-O and M-(O-H)⋯O distances and M-O(H)⋯O bond angles are reported for the hydrated magnesium(II), aluminium(III), manganese(II), iron(II), iron(III), cobalt(II), nickel(II), copper(II) and zinc(II) ions; the subscripts I and II denote oxygen atoms in the first and second hydration sphere, respectively. Reported structures of hydrated metal ions in aqueous solution are summarized and evaluated with emphasis on a possible relationship between M-O-O bond angles and bonding character.
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