The analytical properties of 1-phenyl-1,2-propanedione-2-oxime thiosemi-carbazone (PPDOT) are described for the first time. The reagent gives colour reactions with copper(II) and nickel(II) in sodium acetate-acetic acid buffer medium. The copper complex shows maximum absorbance at 465 nm while the nickel complex at 395 nm. Therefore, these colour reactions have been advantageously used for the simultaneous spectrophotometric determination of copper(II) and nickel(II) in synthetic mixture and also in edible oils and seeds.

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http://dx.doi.org/10.1016/s0039-9140(02)00543-xDOI Listing

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Dalton Trans

September 2024

Department of Molecular Sciences, Swedish University of Agricultural Sciences, P.O. Box 7015, SE-750 07 Uppsala, Sweden.

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