Quantitative separations of microgram quantities of osmium and ruthenium from large proportions of copper, iron and nickel were accomplished by the use of anion-exchange paper. Accurate determinations of osmium and ruthenium were made by adaptation of X-ray fluorescence. Wet methods for the dissolution of the paper and exchanger and subsequent wet determinations of osmium and ruthenium are discussed.
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http://dx.doi.org/10.1016/0039-9140(68)80123-7 | DOI Listing |
Chemistry
January 2025
Department of Chemistry, Indian Institute of Technology Guwahati, 781039, Guwahati, Assam, India.
Oxidative cleavage of olefins is a useful reaction in organic synthesis. The most well-known catalytic system is the osmium based Lemieux-Johnson catalyst, which generally requires high catalyst loading and tends to suffer from rapid overoxidation to produce the acid predominantly. Hence, the development of a mild, general, and selective method toward the oxidative cleavage of alkenes to carbonyl compounds is highly desired.
View Article and Find Full Text PDFFront Biosci (Landmark Ed)
August 2024
Department of Laboratory of Environmental and Food Hygiene, Department of Medical, Surgical Sciences and Advanced Technologies "GF Ingrassia", University of Catania, 95123 Catania, Italy.
Background: The six Platinum group metal elements (PGEs) comprising Ruthenium, Rhodium, Palladium, Platinum, Iridium and Osmium are grouped together in the periodic table. Human activities are mostly responsible for releasing PGEs into the environment. This systematic review focused on three PGEs with the greatest anthropogenic use, including in vehicle catalytic converters: Platinum (Pt), Palladium (Pd), and Rhodium (Rh).
View Article and Find Full Text PDFChemistry
October 2024
IMDEA Nanociencia, Faraday 9, 28049, Madrid, Spain.
Half-sandwich Ru(II)- and Os(II)-arene complexes have great potential for catalytic and biological applications. The possibility of fine-tuning their chemical reactivity by including modifications in the ligands around the metal adds to their many advantages. However, structural modifications at the η-bound arene have had significant synthetic limitations, particularly in the design of Os(II)-tethered complexes.
View Article and Find Full Text PDFWater Res
November 2024
School of Mechanical and Electrical Engineering, University of Electronic Science and Technology of China, Chengdu, China. Electronic address:
Considering the circular economy and environmental protection, sustainable recovery of high-value metals from wastewater has become a prominent concern. Unlike conventional methods featuring extensive chemicals or energy consumption, membrane separation technology plays a crucial role in facilitating the sustainable and efficient recovery of valuable metals from wastewater due to its attractive features. In this review, we first briefly summarize the sustainable supply chain and significance of sustainable recovery of aqueous high-value metals.
View Article and Find Full Text PDFInorg Chem Front
August 2024
Department of Chemistry and Chemical Biology, Cornell University Ithaca NY 14853 USA
The transmembrane protein known as the mitochondrial calcium uniporter (MCU) mediates the influx of calcium ions (Ca) into the mitochondrial matrix. An overload of mitochondrial Ca ( Ca) is directly linked to damaging effects in pathological conditions. Therefore, inhibitors of the MCU are important chemical biology tools and therapeutic agents.
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