Photoluminescent Mn4 single-molecule magnet.

Inorg Chem

Department of Chemistry and Biochemistry, University of California at San Diego, La Jolla, California 92093-0358, USA.

Published: December 2008

The synthesis of [Mn(4)(anca)(4)(Hmdea)(2)(mdea)(2)].2CHCl(3) (1) is reported along with room temperature fluorescence, UV-vis, and NMR spectra. Direct current magnetization versus field data reveal a S = 8 ground state. Quantized steps in temperature- and field-dependent magnetization versus field hysteresis loops confirm single-molecule magnet behavior.

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Source
http://dx.doi.org/10.1021/ic801485kDOI Listing

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