Low-temperature scanning tunneling microscopy of atomically flat Ga(001) islands revealed the 2D electronic superlattice composed of stripe domains. Tunnel spectroscopy of these surface electrons indicates the formation of a 2D charge-ordered state of Wigner-crystal type driven by competition of short-range and long-range Coulomb energies. At the boundaries of stripe domains the energy spectra exhibit splitting due to charged excitonic states and shift due to charge doping, altogether indicating the self-assembly of 1D hole stripes. The size distribution of stripe domains is broadened around 4a.
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