Auger cascade decay processes are of critical importance in x-ray-induced biological damage, chemical reactions, and desorption. Here, we report the first measurements of the isolated energy spectra of electrons emitted during the later steps of an Auger cascade process in a solid (MnO). The large widths and energy gains observed in cascade-induced Mn MVV Auger spectra (as compared to the spectra resulting from direct photoexcitation of the M core hole) provide strong evidence that valence holes created in previous cascade steps participate dynamically in later cascade steps.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1103/PhysRevLett.101.127601 | DOI Listing |
Nano Lett
October 2024
Department of Molecular Chemistry and Materials Science, Weizmann Institute of Science, Rehovot 7610001, Israel.
J Chem Theory Comput
October 2024
Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S. Cass Avenue, Lemont, Illinois 60439, United States.
Phys Rev Lett
August 2024
Institut für Kernphysik, Goethe-Universität Frankfurt, Max-von-Laue-Straße 1, 60438 Frankfurt am Main, Germany.
We use one-photon excitation to promote K-shell electrons of formic acid (which has a planar equilibrium structure) to an antibonding π^{*} orbital. The excited molecule is known to have a (chiral) pyramidal equilibrium structure. In our experiment, we determine the handedness of the excited molecule by imaging the momenta of charged fragments, which occur after its Coulomb explosion triggered by Auger-Meitner decay cascades succeeding the excitation.
View Article and Find Full Text PDFPhys Rev Lett
June 2024
Sorbonne Université, CNRS, UMR 7095, Institut d'Astrophysique de Paris, 98 bis bd Arago, 75014 Paris, France.
Next-generation radio experiments such as the radio detector of the upgraded Pierre Auger Observatory and the planned GRAND and BEACON arrays target the detection of ultra-high-energy particle air showers arriving at low elevation angles. These inclined cosmic-ray air showers develop higher in the atmosphere than vertical ones, enhancing magnetic deflections of electrons and positrons inside the cascade. We evidence two novel features in their radio emission: a new polarization pattern, consistent with a geosynchrotron emission model and a coherence loss of the radio emission, both for showers with zenith angle θ≳65° and strong enough magnetic field amplitude (typical strength of B∼50 μT).
View Article and Find Full Text PDFPhys Rev Lett
February 2024
Laboratory for Physical Chemistry, ETH Zürich, Vladimir-Prelog-Weg 2, 8093 Zürich, Switzerland.
We introduce time-resolved multielectron coincidence spectroscopy and apply it to the double Auger-Meitner (AM) emission process following xenon 4d photoionization. The photoelectron and AM electron(s) are measured in coincidence by using a magnetic-bottle time-of-flight spectrometer, enabling an unambiguous assignment of the complete cascade pathways involving two AM electron emissions. In the presence of a near-infrared (NIR) laser pulse, the intermediate Xe^{2+*} state embedded in the Xe^{3+} continuum is probed through single NIR photon absorption and the lifetime of this intermediate Xe^{2+*} state is directly obtained as (109±22) fs.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!