Extensive two-dimensional Langevin dynamics simulations are used to determine the effect of steady shear flows on the crystal nucleation kinetics of charge stabilized colloids and colloids whose pair potential possess an attractive shallow well of a few k_{B}T 's (attractive colloids). Results show that in both types of systems small amounts of shear speeds up the crystallization process and enhances the quality of the growing crystal significantly. Moderate shear rates, on the other hand, destroy the ordering in the system. The very high shear rate regime where a reentering transition to the ordered state could exist is not considered in this work. In addition to the crystal nucleation phenomena, the analysis of the transport properties and the characterization of the steady state regime under shear are performed.
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http://dx.doi.org/10.1103/PhysRevE.78.031403 | DOI Listing |
Adv Mater
January 2025
Michael Grätzel Center for Mesoscopic Solar Cells Wuhan National Laboratory for Optoelectronics Key Laboratory of Materials Chemistry for Energy Conversion and Storage of Ministry of Education, Huazhong University of Science and Technology, Wuhan, Hubei, 430074, P. R. China.
Carbon-based printable mesoscopic solar cells (p-MPSCs) offer significant advantages for industrialization due to their simple fabrication process, low cost, and scalability. Recently, the certified power conversion efficiency of p-MPSCs has exceeded 22%, drawing considerable attention from the community. However, the key challenge in improving device performance is achieving uniform and high-quality perovskite crystallization within the mesoporous structure.
View Article and Find Full Text PDFJ Chem Phys
January 2025
Institute of Photoelectronic Thin Film Devices and Technology, Tianjin Key Laboratory of Thin Film Devices and Technology, Nankai University, Tianjin 300350, China.
Kesterite Cu2ZnSn(S,Se)4 (CZTSSe) has emerged as a promising photovoltaic material due to its low cost and high stability. The CZTSSe film for high-performance solar cells can be obtained by annealing the deposited CZTS precursor films with selenium (a process known as selenization). The design of the selenization process significantly affects the quality of the absorber layer.
View Article and Find Full Text PDFACS Nano
January 2025
Division of Materials Science and Engineering, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea.
Although the use of ultraviolet (UV) light-emitting diode backlight with red, green, and blue color-conversion layers (CCLs) in displays simplifies the manufacturing process and improves display uniformity, research on blue CCLs remains limited and has been mostly reported in the sky-blue region (> 470 nm), which is insufficient to satisfy the Rec. 2020 color standard. As halide perovskites offer a high extinction coefficient, color purity, and photoluminescence quantum yield (PLQY), they become highly competitive color-converting materials for CCLs.
View Article and Find Full Text PDFACS Nano
January 2025
Department of Physics, National University of Singapore, Singapore 117551, Singapore.
Phase separation plays a crucial role in many natural and industrial processes, such as the formation of clouds and minerals and the distillation of crude oil. In metals and alloys, phase separation is an important approach often utilized to improve their mechanical strength for use in construction, automobile, and aerospace manufacturing. Despite its importance in many processes, the atomic details of phase separation are largely unknown.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
State Key Laboratory of Chemical Engineering, Shanghai Key Laboratory of Multiphase Materials Chemical Engineering, School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China. Electronic address:
Branched poly (butylene succinate-co-butylene terephthalate) (BPBST) was synthesized by in-situ polycondensation to enhance the foamability of poly (butylene succinate-co-butylene terephthalate) (PBST) and was blended with cellulose nanocrystals (CNC) to address foam shrinkage. The introduction of 2 wt% CNC increased the crystallization temperature of BPBST from 66.6 °C to 87.
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