Although 1,3-dioxoindane-2-carboxylic acid is highly unstable, its enamino derivatives can be isolated by careful hydrolysis of their esters with 2,4-dihydroxy-1,4-naphthoquinone. Crystal structure determination reveals the formation of two intramolecular hydrogen bonds, offering thus a possible explanation for the stability of these acids.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/jo8014903 | DOI Listing |
Publication Analysis
Top Keywords
enamino derivatives
8
13-dioxoindane-2-carboxylic acid
8
derivatives 13-dioxoindane-2-carboxylic
4
acid 13-dioxoindane-2-carboxylic
4
acid highly
4
highly unstable
4
unstable enamino
4
derivatives isolated
4
isolated careful
4
careful hydrolysis
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!