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Palladium-catalyzed direct arylation of nitro-substituted aromatics with aryl halides. | LitMetric

Palladium-catalyzed direct arylation of nitro-substituted aromatics with aryl halides.

Org Lett

Centre for Catalysis Research and Innovation, Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Canada K1N 6N5.

Published: October 2008

AI Article Synopsis

Article Abstract

Direct arylation reactions of nitrobenzenes and aryl halides occur in good yield and high ortho regioselectivity. These reactions can be performed on gram scale with as few as 3 equiv of the nitro arene relative to the aryl halide. The synthetic utility of this method is demonstrated via rapid synthesis of a Boscalid intermediate.

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Source
http://dx.doi.org/10.1021/ol801839wDOI Listing

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