L-(-)-sucrose was efficiently synthesized using intramolecular aglycon delivery and used to elucidate osmotic effects on the activity of invertase, which catalyzes the hydrolysis of D-(+)-sucrose. The osmotic effect imposed by L-sucrose was responsible for more than 30% of the activity loss ascribed otherwise to "substrate inhibition."
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2588412 | PMC |
| http://dx.doi.org/10.1039/b810158b | DOI Listing |
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