To measure the concentrations of yttrium-oxide-coated small-dispersed silicon nitride plasma powder, the air was aspirated at the amount of 10-15 litres per min through the AFA-XP filter. The filter was limed in a platinum crucible, the residuum being alloyed with Na2CO3, Na2B4O7, NaNO3 in ratio 10:5:1. The alloy was transferred into solution in which the silicon content was assessed through reactions with ammonium molybdate, and yttrium--through reactions with arsenaso III. The sensibility rate for silicon was at 0.07 mg/m3.
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ACS Appl Mater Interfaces
January 2025
Division of Micro and Nanosystems (MST), School of Electrical Engineering and Computer Science (EECS), KTH Royal Institute of Technology, Stockholm SE-10044, Sweden.
Controlled breakdown has emerged as an effective method for fabricating solid-state nanopores in thin suspended dielectric membranes for various biomolecular sensing applications. On an unpatterned membrane, the site of nanopore formation by controlled breakdown is random. Nanopore formation on a specific site on the membrane has previously been realized using local thinning of the membrane by lithographic processes or laser-assisted photothermal etching under immersion in an aqueous salt solution.
View Article and Find Full Text PDFInd Eng Chem Res
January 2025
Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr, Germany.
This work presents the scale-up of room-temperature mechanochemical synthesis of nanocorundum (high-surface-area α-AlO) from boehmite (γ-AlOOH). This transformation on the 1 g scale using a laboratory shaker mill had previously been reported. High-energy Simoloyer ball mills equipped with milling chambers of sizes ranging from 1 to 20 L were used to scale up the mechanochemical nanocorundum synthesis to the 50 g to 1 kg scale, which paves the way to further increase batch size.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Biomedical Engineering, University of Rochester, Rochester, NY, USA.
The aberrant vascular response associated with tendon injury results in circulating immune cell infiltration and a chronic inflammatory feedback loop leading to poor healing outcomes. Studying this dysregulated tendon repair response in human pathophysiology has been historically challenging due to the reliance on animal models. To address this, our group developed the human tendon-on-a-chip (hToC) to model cellular interactions in the injured tendon microenvironment; however, this model lacked the key element of physiological flow in the vascular compartment.
View Article and Find Full Text PDFJ Mech Behav Biomed Mater
January 2025
School of Materials Science and Engineering, University of Jinan, Jinan, 250022, China. Electronic address:
Silicon nitride (Si₃N₄) ceramics exhibit excellent mechanical properties and biocompatibility, making them highly suitable for biomedical applications, particularly in implants. In this study, the mechanical properties and bioactivity of Si₃N₄ ceramics with varying amounts of Y₂O₃-Al₂O₃-SiO₂ sintering aids were investigated. Increasing the sintering additive content from 4 wt% to 8 wt% substantially improved the bulk density of the ceramics, leading to notable enhancements in mechanical properties.
View Article and Find Full Text PDFBiosensors (Basel)
January 2025
INFN-Laboratori Nazionali di Frascati, Via E. Fermi 54, 00044 Frascati, Italy.
The COVID-19 pandemic has highlighted the urgent need for rapid, sensitive, and reliable diagnostic tools for detecting SARS-CoV-2. In this study, we developed and optimized a surface plasmon resonance (SPR) biosensor incorporating advanced materials to enhance its sensitivity and specificity. Key parameters, including the thickness of the silver layer, silicon nitride dielectric layer, molybdenum disulfide (MoS) layers, and ssDNA recognition layer, were systematically optimized to achieve the best balance between sensitivity, resolution, and attenuation.
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