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Critical swelling of particle-encapsulating vesicles. | LitMetric

Critical swelling of particle-encapsulating vesicles.

Phys Rev Lett

School of Chemistry, Raymond & Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, Tel Aviv 69978, Israel.

Published: August 2008

AI Article Synopsis

Article Abstract

We consider a ubiquitous scenario where a fluctuating, semipermeable vesicle is embedded in solution while enclosing a fixed number of solute particles. The swelling with increasing number of particles or decreasing concentration of the outer solution exhibits a continuous phase transition from a fluctuating state to the maximum-volume configuration, whereupon appreciable pressure difference and surface tension build up. This criticality is unique to particle-encapsulating vesicles, whose volume and inner pressure both fluctuate. It implies a universal swelling behavior of such vesicles as they approach their limiting volume and osmotic lysis.

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http://dx.doi.org/10.1103/PhysRevLett.101.078104DOI Listing

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