The dynamics of confined systems is of major concern for both fundamental physics and applications. In this Letter, the dynamics of C60 fullerene molecules inside single walled carbon nanotubes is studied using inelastic neutron scattering. We identify the C60 vibrations and highlight their sensitivity to temperature. Moreover, a clear signature of rotational diffusion of the C60 is evidenced, which persists at lower temperature than in 3D bulk C60. It is discussed in terms of confinement and of reduced dimensionality of the C60 chain.
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http://dx.doi.org/10.1103/PhysRevLett.101.065507 | DOI Listing |
Adv Sci (Weinh)
January 2025
Haiping Fang, School of Physics, East China University of Science and Technology, Shanghai, 20023, China.
The human visual nervous system excels at recognizing and processing external stimuli, essential for various physiological functions. Biomimetic visual systems leverage biological synapse properties to improve memory encoding and perception. Optoelectronic devices mimicking these synapses can enhance wearable electronics, with layered heterojunction materials being ideal materials for optoelectronic synapses due to their tunable properties and biocompatibility.
View Article and Find Full Text PDFJ Mol Model
January 2025
Department of Astronautic Science and Mechanics, Harbin Institute of Technology, Harbin, 150006, People's Republic of China.
Context: The influence of fullerene C60 on the mechanical and thermal properties of natural rubber was systematically investigated using coarse-grained molecular dynamics simulations. The tensile results demonstrate that systems with longer NR chains exhibit reduced tensile strength. Moreover, the addition of C60 nanoparticles significantly enhanced the mechanical properties, with Young's modulus, yield strength, and tensile strength increasing by approximately 24.
View Article and Find Full Text PDFACS Omega
January 2025
Department of Functional Materials, FZU - Institute of Physics - Czech Academy of Sciences, Na Slovance 1999/2, Prague 8 182 00, Czech Republic.
Here, we investigate the interactions between five representative gaseous analytes and two poly(ionic liquids) (PILs) based on the sulfopropyl acrylate polyanion in combination with the alkylphosphonium cations, P and P, and their nanocomposites with fullerenes (C, C) to reveal the potential of PILs as sensitive layers for gas sensors. The gaseous analytes were chosen based on their molecular size (all of them containing two carbon atoms) and variation of functional groups: alcohol (ethanol), nitrile (acetonitrile), aldehyde (acetaldehyde), halogenated alkane (bromoethane), and carboxylic acid (acetic acid). The six variations of PILs-PSPA (), PSPA + C ( + C), PSPA + C ( + C), and PSPA (), PSPA + C ( + C), PSPA + C ( + C)-were characterized by UV-vis and Raman spectroscopy, and their interactions with each gaseous analyte were studied using electrochemical impedance spectroscopy.
View Article and Find Full Text PDFJ Chem Phys
December 2024
Department of Chemistry, Kyushu University, Fukuoka 812-0395, Japan.
To analyze hydration effects on macromolecular diffusion, the friction coefficients of macromolecules were examined using molecular dynamics simulations with an all-atom model. In the present study, a method was introduced to decompose the molecular friction coefficient into the contributions for each site on the macromolecule. The method was applied to several fullerenols in ambient water.
View Article and Find Full Text PDFChem Commun (Camb)
January 2025
Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan.
The diiridium complexes of lithium-ion endohedral fullerene Li@C were synthesised in high yields. X-ray crystallography revealed the η:η-coordination of Li@C and the disorder of the Li ion over two sites close to the coordinated carbons. C NMR study suggested the presence of dynamic behaviour haptotropic rearrangements.
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