This work describes the fabrication, characterization, and biological evaluation of a thin protein-resistant poly(ethylene glycol) (PEG)-based hydrogel coating for antifouling applications. The coating was fabricated by free-radical polymerization on silanized glass and silicon and on polystyrene-covered silicon and gold. The physicochemical properties of the coating were characterized by infrared spectroscopy, ellipsometry, and contact angle measurements. In particular, the chemical stability of the coating in artificial seawater was evaluated over a six-month period. These measurements indicated that the degradation process was slow under the test conditions chosen, with the coating thickness and composition changing only marginally over the period. The settlement behavior of a broad and diverse group of marine and freshwater fouling organisms was evaluated. The tested organisms were barnacle larvae (Balanus amphitrite), algal zoospores (Ulva linza), diatoms (Navicula perminuta), and three bacteria species (Cobetia marina, Marinobacter hydrocarbonoclasticus, and Pseudomonas fluorescens). The biological results showed that the hydrogel coating exhibited excellent antifouling properties with respect to settlement and removal.
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Mar Pollut Bull
January 2025
Department of Materials Science and Engineering, Dalian Maritime University, Dalian 116026, PR China; Dalian Key Laboratory of Internal Combustion Engine Tribology and Reliability Engineering, Dalian 116026, PR China. Electronic address:
As a global challenge, marine biofouling is causing serious economic losses and adverse ecological impacts. In recent years, a variety of promising and environmentally friendly anti-fouling strategies have emerged, among which the excellent anti-fouling performance of bionic autocrine coatings has been recognized. However, bionic autocrine coatings still suffer from uncontrollable secretion behavior, poor mechanical stability, and poor abrasion resistance.
View Article and Find Full Text PDFTalanta
January 2025
College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, 541004, China.
Monitoring reactive nitrogen species (RNS) in complex biological media is essential for evaluating the health status of living organisms; however, biofouling on the sensor surface restricts its applications. To overcome this issue, we developed an antifouling electrochemical sensing platform using copper-platinum bimetallic nanoparticles/N-doped biomass porous carbon fibres (Cu-PtNPs/N-BCF) for directly detecting peroxynitrite anion (ONOO), a major type of RNS. Cyclic voltammetry measurements demonstrated that the Cu-PtNPs/N-BCF-2 nanocomposite, synthesised at a molar ratio of 1:1 between Co and Zn, exhibited exceptional electrocatalytic activity for ONOO oxidation.
View Article and Find Full Text PDFNanoscale
January 2025
College of Materials Science and Engineering, Hubei Provincial Engineering Research Center of Industrial Fiber Preparation and Application, Wuhan Textile University, Wuhan 430200, Hubei, China.
In recent years, solar-driven photothermal water evaporation technology for seawater desalination and wastewater treatment has developed rapidly, which is of great significance for addressing the issue of freshwater scarcity. However, due to the high costs associated with the manufacturing, maintenance, and operation of such devices, their application remains challenging in remote and resource-scarce regions. Due to its excellent light absorption capability in the near-infrared region, high hydrophilicity, and stable chemical properties, coupled with the low cost of recycling waste carbonized polyphenylene sulfide, this material is an excellent choice as a photothermal material for solar-driven water evaporation devices.
View Article and Find Full Text PDFQ Rev Biophys
January 2025
Institute of Synthetic Bioarchitectures, Department of Bionanosciences, University of Natural Resources and Life Sciences, Vienna, Austria.
Prokaryotic microorganisms, comprising and , exhibit a fascinating diversity of cell envelope structures reflecting their adaptations that contribute to their resilience and survival in diverse environments. Among these adaptations, surface layers (S-layers) composed of monomolecular protein or glycoprotein lattices are one of the most observed envelope components. They are the most abundant cellular proteins and represent the simplest biological membranes that have developed during evolution.
View Article and Find Full Text PDFLangmuir
January 2025
School of Chemical Engineering, Department of Chemistry and Materials Science, Aalto University, Tietotie 3 Espoo 02150, Finland.
Superhydrophobic surfaces find applications in numerous biomedical scenarios, requiring the repellence of biofluids and biomolecules. Plastron, the trapped air between a superhydrophobic surface and a wetting liquid, plays a pivotal role in biofluid repellency. A key challenge, however, is the often short-lived plastron stability in biofluids and the lack of knowledge surrounding it.
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