Geobacter sulfurreducens reduced Ag(I) (as insoluble AgCl or Ag(+) ions), via a mechanism involving c-type cytochromes, precipitating extracellular nanoscale Ag(0). These results extend the range of metals known to be reduced by Geobacter species and offer a method for recovering silver from contaminated water as potentially useful silver nanoparticles.
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http://dx.doi.org/10.1128/AEM.01069-08 | DOI Listing |
ACS Biomater Sci Eng
December 2024
Department of Physics and Astronomy, University of Southern California, Los Angeles, California 90089, United States.
Electroactive microorganisms such as can couple organic electron donor oxidation to the respiration of electrode surfaces, colonizing them in the process. These microbes can also reduce soluble metal ions, such as soluble Pd, resulting in metallic nanoparticle (NP) synthesis. Such NPs are valuable catalysts for industrially relevant chemical production; however, their chemical and solid-state syntheses are often energy-intensive and result in hazardous byproducts.
View Article and Find Full Text PDFBiochem J
December 2024
Associate Laboratory i4HB - Institute for Health and Bioeconomy, NOVA School of Science and Technology, Universidade NOVA de Lisboa, 2829-516 Caparica, Portugal.
Geobacter's unique ability to perform extracellular electron transfer (EET) to electrodes in microbial fuel cells (MFCs) has sparked the implementation of sustainable production of electrical energy. However, the electrochemical performance of Geobacter's biofilms in MFCs remains challenging to implement industrially. Multiple approaches are being investigated to enhance MFC technologies.
View Article and Find Full Text PDFWater Res
November 2024
Department of Civil, Construction, and Environmental Engineering, The University of Alabama, Tuscaloosa, AL 35487, USA. Electronic address:
Selenium pollution in aquatic environments poses a major global challenge, with a significant gap in effective treatment technologies. In this study, we explored a novel approach integrating flow-electrode capacitive deionization (FCDI) with bio-electrochemical systems (BES) for the removal and reduction of selenate and selenite ions in one compact reactor. Our integrated system was electricity-driven, eliminating chemical usage.
View Article and Find Full Text PDFN Biotechnol
November 2024
Institute of Technical Microbiology, Hamburg University of Technology, Hamburg 21073, Germany. Electronic address:
Microbial electrochemical systems offer a sustainable method for the conversion of chemical energy into electrical energy or hydrogen and the production of valuable compounds, contributing to the development of a bio-based economy. This study aimed to enhance the performance of anodic bioelectrochemical systems by improving the current density of Shewanella oneidensis as a biocatalyst through strain modification and medium refinement. The genetic modification, combining the prophage deletion and overexpression of the speC gene, resulted in a 4.
View Article and Find Full Text PDFEnviron Sci Technol
December 2024
Southwest United Graduate School, Kunming 650092, China.
Molybdenum (Mo) is an essential nutrient for almost all organisms. However, at high concentrations, it can be toxic to animals and plants. This study investigated the interactions of Mo(VI) with iron oxyhydroxides during ferrihydrite bioreduction in the presence of Fe(III)-reducing .
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