The complex TpW(NO)(PMe3)(eta(2)-anisole) is combined with acrolein or methyl vinyl ketone and various nucleophiles to generate novel chromen complexes. These complexes may be further elaborated by protonation and nucleophilic addition to generate chroman analogues with increased saturation and stereocenters. Treatment with various oxidants effects the decomplexation of the chromen.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/ja803605m | DOI Listing |
Publication Analysis
Top Keywords
synthesis 1-oxadecalins
4
1-oxadecalins anisole
4
anisole promoted
4
promoted tungsten
4
tungsten complex
4
complex tpwnopme3eta2-anisole
4
tpwnopme3eta2-anisole combined
4
combined acrolein
4
acrolein methyl
4
methyl vinyl
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!