A conjoined thienopyrrole oligomer formed by using DNA as a molecular guide.

Org Lett

School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332, USA.

Published: September 2008

AI Article Synopsis

Article Abstract

A thienopyrrole oligomer conjoined to DNA was prepared by means of a templated synthesis protocol. The oligomer was formed by reaction, initiated with HRP/H2O2, of thieno[3,2-b]pyrrole monomers attached to cytosine bases. The thienopyrrole oligomer was characterized spectroscopically.

Download full-text PDF

Source
http://dx.doi.org/10.1021/ol801137tDOI Listing

Publication Analysis

Top Keywords

thienopyrrole oligomer
12
oligomer formed
8
conjoined thienopyrrole
4
oligomer
4
formed dna
4
dna molecular
4
molecular guide
4
guide thienopyrrole
4
oligomer conjoined
4
conjoined dna
4

Similar Publications

Spectroscopic Study of Thiophene-Pyrrole-Containing S,N-Heteroheptacenes Compared to Acenes and Phenacenes.

J Phys Chem B

August 2017

Institute of Organic Chemistry II and Advanced Materials, University of Ulm, Albert-Einstein-Allee 11, 89081 Ulm, Germany.

In this study, we report a detailed spectroscopic study concerning the energy levels and vibrational structure of thiophene-pyrrole-containing S,N-heteroacenes. The aim of the study is first, to understand the differences in the photoluminescence (PL) efficiencies in this structurally similar series and second, to compare the electronic structure of S,N-heteroacenes to that of linear acenes and phenacenes, with a view to derive guidelines for the design of singlet fission materials. For S,N-heteroacenes comprising seven fused heterocyclic rings, we observe a higher PL quantum yield for derivatives with terminal thienothiophene units than for thienopyrrole-capped ones.

View Article and Find Full Text PDF

A conjoined thienopyrrole oligomer formed by using DNA as a molecular guide.

Org Lett

September 2008

School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332, USA.

A thienopyrrole oligomer conjoined to DNA was prepared by means of a templated synthesis protocol. The oligomer was formed by reaction, initiated with HRP/H2O2, of thieno[3,2-b]pyrrole monomers attached to cytosine bases. The thienopyrrole oligomer was characterized spectroscopically.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!