Binuclear organometallic ruthenium complexes of a Schiff base expanded porphyrin.

Chem Commun (Camb)

Department of Chemistry and Biochemistry, University of Texas, 1 University Station A5300, Austin, TX 78712-0165, USA.

Published: August 2008

The synthesis of binuclear organometallic ruthenium complexes of an expanded porphyrin-type macrocycle is reported; pyrrolic hydrogen bonding donors were found to interact with ancillary ligands in the primary coordination sphere and to stabilize coordinated dioxygen in an eta(2)-fashion.

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Source
http://dx.doi.org/10.1039/b807126hDOI Listing

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