To evaluate the efficiency and the influence of thermal desorption on the soil organic compartment, contaminated soils from coking plant sites (NM and H) were compared to their counterparts treated with thermodesorption. The extractable organic matter, and the metal content and distribution with soil compartments were studied. In both thermodesorbed soils, PAH (polycyclic aromatic hydrocarbon) degradation exceeded 90%. However, the thermal desorption led not only to a volatilization of the organic compounds but also to the condensation of extractable organic matter. The treatments only affected the Fe and Zn distribution within the more stable fractions, whereas the organic compound degradation did not affect their mobility and availability.
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http://dx.doi.org/10.1016/j.envpol.2008.06.020 | DOI Listing |
Materials (Basel)
January 2025
Departamento de Química Ambiental, Universidad Católica de la Santísima Concepción, Concepción 4070129, Chile.
This study evaluated the stability and reusability of amino-functionalized nanocellulose aerogels as CO-adsorbent materials. The modified aerogels, synthesized via a controlled silylation using N-[3-(trimethoxysilyl) propyl] ethylenediamine (DAMO), demonstrated excellent thermal stability up to 250 °C (TGA) and efficient CO adsorption through chemisorption, which was the main adsorption mechanism. The performance of the aerogels was assessed using both adsorption isotherms and the decay pressure technique, revealing that CO adsorption capacity increased with higher amino group loading (4.
View Article and Find Full Text PDFEcotoxicol Environ Saf
January 2025
National Institute of Environmental Health, Chinese Center for Disease Control and Prevention, Beijing 100021, China; China CDC Key Laboratory of Environment and Population Health, Beijing 100021, China. Electronic address:
Cognitive fatigue in specific occupations may present a risk to personal safety. The study aimed to explore the characteristic volatile organic compounds (VOCs) in exhaled breath in response to cognitive fatigue, to provide a scientific basis for the non-invasive exhaled breath diagnostic techniques for cognitive fatigue assessing. Thirty healthy young adults were recruited and assigned to complete two 1.
View Article and Find Full Text PDFNanomaterials (Basel)
January 2025
State Key Laboratory of High-Performance Civil Engineering Materials, Jiangsu Sobute New Materials Co., Ltd., Nanjing 210008, China.
A novel class of SiO aerogel-based resin composite with a self-formed foamy structure and an extremely low thermal conductivity, as well as excellent fire resistance, was fabricated via a room temperature and atmospheric pressure route. The self-formed foamy structure was achieved by utilizing SiO aerogel particles not only as a thermal insulative functional additive filler but also as nano-sized solid particles in a Picking emulsion system, adjusting the surface tension as a stabilizer at the interface between the two immiscible phases (liquid and air in this case). The results of foamy structure analyses via scanning electron microscopy, micro-CT, and N adsorption-desorption isotherms validate the successful generation of a micro-scale porous structure with the enhancement of the aerogel nano-scale solid particles at the wall as a stabilizer.
View Article and Find Full Text PDFCarbohydr Polym
March 2025
Heilongjiang Green Food Science Research Institute, Northeast Agricultural University, Harbin 150030, China; College of Food Science, Northeast Agricultural University, Harbin 150030, China.
Polysaccharide-based metal-organic frameworks have attracted widespread attention due to their combination of the biocompatibility and flexibility of polysaccharides. Cyclodextrin are interesting bio-ligands in the construction of polysaccharide-based MOFs. Conventional methods for preparing cyclodextrin metal-organic frameworks (CD-MOFs) are often time-consuming and inefficient.
View Article and Find Full Text PDFLangmuir
January 2025
Department of Engineering Science, University of Oxford, Oxford OX1 3PJ, United Kingdom.
Mass transfer governs the overall catalytic performance of heterogeneous catalysts considerably; however, this fundamental research has often been ignored. Here, macroporous SiO-supported Pt nanoparticle (Pt/SiO-M) and mesoporous SiO-supported Pt nanoparticle (Pt/SiO-m) catalysts were specifically fabricated by a facile thermal reduction step to engineer the resultant Pt nanoparticles showing similar physiochemical properties while possessing completely different porous microstructures exclusively originating from SiO supports. On this basis, a platform to explore the crucial mass transfer difference affecting catalytic activity is then established by systematically practicing industry-important benzene oxidation measurements.
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